发明公开
EP1397371A1 METALLOCENES AND THEIR USE IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS
有权
茂金属,USE IN催化剂的烯烃聚合
- 专利标题: METALLOCENES AND THEIR USE IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS
- 专利标题(中): 茂金属,USE IN催化剂的烯烃聚合
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申请号: EP02748826.1申请日: 2002-06-20
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公开(公告)号: EP1397371A1公开(公告)日: 2004-03-17
- 发明人: FRITZE, Cornelia , RESCONI, Luigi , SCHULTE, Jörg , GUIDOTTI, Simona
- 申请人: Basell Polyolefine GmbH
- 申请人地址: Brühler Strasse 60 50389 Wesseling DE
- 专利权人: Basell Polyolefine GmbH
- 当前专利权人: Basell Polyolefine GmbH
- 当前专利权人地址: Brühler Strasse 60 50389 Wesseling DE
- 代理机构: Colucci, Giuseppe
- 优先权: EP01202413 20010622
- 国际公布: WO2003000706 20030103
- 主分类号: C07F17/00
- IPC分类号: C07F17/00 ; C07F7/08 ; C08F10/00
摘要:
A metallocene compound of formula (I): wherein M is zirconium, titanium and hafnium; X is a hydrogen atom, a halogen atom or a hydrocarbon radical; R1 is a linear C¿1?-C20-alkyl radical; R?2¿ is a hydrogen atom or hydrocarbon R?3, R4, R5, R6, R7, and R8¿, are hydrogen atoms or hydrocarbon radicals, A is a sulphur (S) atom or an oxygen (O) atom; Q is a radical of formula (II), (III) or (IV) being bonded to the indenyl at the position indicated by the symbol *; (II), (III), (IV) wherein T1 is a sulphur atom, an oxygen (O) atom or a NR; R?9, R10 and R11¿ are hydrogen atoms or hydrocarbon radicals; T?2, T3, T4, T5, and T6¿ are carbon atoms (C) or nitrogen atoms (N); m?1, m2, m3, m4 and m5¿ are 0 or 1; R?12, R13, R14, R15 and R16¿ are hydrogen atoms or hydrocarbon radicals with the provisos that at least one of R?12, R13, R14, R15 and R16¿ is different from hydrogen atoms, and that no more than two of T?2, T3, T4, T5 and T6¿ are nitrogen atoms.
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