发明公开
EP1401964A1 COMPOSITION SILICONE RETICULABLE EN ELASTOMERE PAR HYDROSILYLATION, EN PRESENCE DE CATALYSEURS METALLIQUES A BASE DE CARBENES, ET CATALYSEURS DE CE TYPE
有权
通过氢化硅烷化,在金属 - 卡宾配合物存在下,与弹性体可联网的有机硅氧烷组合物和该金属催化剂
- 专利标题: COMPOSITION SILICONE RETICULABLE EN ELASTOMERE PAR HYDROSILYLATION, EN PRESENCE DE CATALYSEURS METALLIQUES A BASE DE CARBENES, ET CATALYSEURS DE CE TYPE
- 专利标题(英): Silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts, and catalysts
- 专利标题(中): 通过氢化硅烷化,在金属 - 卡宾配合物存在下,与弹性体可联网的有机硅氧烷组合物和该金属催化剂
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申请号: EP02747494.9申请日: 2002-06-03
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公开(公告)号: EP1401964A1公开(公告)日: 2004-03-31
- 发明人: GEORGE, Catherine , BLANC-MAGNARD, Delphine , POUCHELON, Alain , STERIN, Sébastien
- 申请人: Rhodia Chimie
- 申请人地址: 26 Quai Alphonse le Gallo 92100 Boulogne Billancourt FR
- 专利权人: Rhodia Chimie
- 当前专利权人: Rhodia Chimie
- 当前专利权人地址: 26 Quai Alphonse le Gallo 92100 Boulogne Billancourt FR
- 代理机构: Trolliet, Maurice
- 优先权: FR0107473 20010607
- 国际公布: WO2002098971 20021212
- 主分类号: C09D4/00
- IPC分类号: C09D4/00 ; C09D183/04 ; C09D179/00 ; C03C1/00 ; C09D185/00 ; C08L83/04 ; C07F15/00 ; C08K5/00
摘要:
The invention concerns a silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts. The invention aims at providing a composition of that type, stable over long periods at room temperature (one day to several months), without loss of its characteristic of being heat-curable by hydrosilylation and without generating secondary isomerization or colouring reactions. The invention is characterised in that the composition comprises: a polyorganovinylsiloxane (polydimethyl)(methylvinyl) siloxane; a polyorganohydrogenosiloxane; a platinum catalyst formed by a complex of formula C3 and optionally an acetylene crosslinking inhibitor; optionally a siliceous filler. The invention also concerns novel hydrosilylation catalysts of the metal complex type of formula C3 above. The life span of the potted single-constituent compositions of the invention is significantly increased.
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