发明公开
EP1401964A1 COMPOSITION SILICONE RETICULABLE EN ELASTOMERE PAR HYDROSILYLATION, EN PRESENCE DE CATALYSEURS METALLIQUES A BASE DE CARBENES, ET CATALYSEURS DE CE TYPE 有权
通过氢化硅烷化,在金属 - 卡宾配合物存在下,与弹性体可联网的有机硅氧烷组合物和该金属催化剂

  • 专利标题: COMPOSITION SILICONE RETICULABLE EN ELASTOMERE PAR HYDROSILYLATION, EN PRESENCE DE CATALYSEURS METALLIQUES A BASE DE CARBENES, ET CATALYSEURS DE CE TYPE
  • 专利标题(英): Silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts, and catalysts
  • 专利标题(中): 通过氢化硅烷化,在金属 - 卡宾配合物存在下,与弹性体可联网的有机硅氧烷组合物和该金属催化剂
  • 申请号: EP02747494.9
    申请日: 2002-06-03
  • 公开(公告)号: EP1401964A1
    公开(公告)日: 2004-03-31
  • 发明人: GEORGE, CatherineBLANC-MAGNARD, DelphinePOUCHELON, AlainSTERIN, Sébastien
  • 申请人: Rhodia Chimie
  • 申请人地址: 26 Quai Alphonse le Gallo 92100 Boulogne Billancourt FR
  • 专利权人: Rhodia Chimie
  • 当前专利权人: Rhodia Chimie
  • 当前专利权人地址: 26 Quai Alphonse le Gallo 92100 Boulogne Billancourt FR
  • 代理机构: Trolliet, Maurice
  • 优先权: FR0107473 20010607
  • 国际公布: WO2002098971 20021212
  • 主分类号: C09D4/00
  • IPC分类号: C09D4/00 C09D183/04 C09D179/00 C03C1/00 C09D185/00 C08L83/04 C07F15/00 C08K5/00
COMPOSITION SILICONE RETICULABLE EN ELASTOMERE PAR HYDROSILYLATION, EN PRESENCE DE CATALYSEURS METALLIQUES A BASE DE CARBENES, ET CATALYSEURS DE CE TYPE
摘要:
The invention concerns a silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts. The invention aims at providing a composition of that type, stable over long periods at room temperature (one day to several months), without loss of its characteristic of being heat-curable by hydrosilylation and without generating secondary isomerization or colouring reactions. The invention is characterised in that the composition comprises: a polyorganovinylsiloxane (polydimethyl)(methylvinyl) siloxane; a polyorganohydrogenosiloxane; a platinum catalyst formed by a complex of formula C3 and optionally an acetylene crosslinking inhibitor; optionally a siliceous filler. The invention also concerns novel hydrosilylation catalysts of the metal complex type of formula C3 above. The life span of the potted single-constituent compositions of the invention is significantly increased.
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