发明公开
- 专利标题: TWO-STEP POLYMERIZATION PROCESS
- 专利标题(中): 两段聚合
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申请号: EP02779649.9申请日: 2002-10-31
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公开(公告)号: EP1448633A1公开(公告)日: 2004-08-25
- 发明人: KALLIO, Kalle , KINNUNEN, Esa , LEHTINEN, Arja , MALMBERG, Anneli , ORA, Marja
- 申请人: Borealis Technology Oy , Campbell, Neil
- 申请人地址: P.O. Box 330 06101 Porvoo FI
- 专利权人: Borealis Technology Oy,Campbell, Neil
- 当前专利权人: Borealis Technology Oy,Campbell, Neil
- 当前专利权人地址: P.O. Box 330 06101 Porvoo FI
- 代理机构: Campbell, Neil Boyd
- 优先权: GB0126147 20011031
- 国际公布: WO2003037941 20030508
- 主分类号: C08F210/16
- IPC分类号: C08F210/16 ; C08F297/08 ; C08F2/14
摘要:
A process for the preparation of homo or copolymers of ethylene, said process comprising: i) in a first polymerisation stage, continuously polymerising ethylene and optionally at least one C3-10 α-olefin, the reaction mixture further comprising a diluent and a metallocene catalyst having at least one optionally substituted indenyl ligand, said first polymerisation stage being effected essentially in the absence of hydrogen and with an ethylene concentration of 0.005 to 25 % mol relative to said diluent, preferably 0.005 to 4 % mol to a yield a polymer slurry; ii) in a second polymerisation stage continuously polymerising the polymer slurry resulting from said first polymerisation stage with the addition of further ethylene and optionally at least one C3-10 α-olefin and optionally hydrogen; wherein the first and second polymerisation stages are so effected that the ratio of the weight of polymer produced in the first polymerisation stage to the weight of polymer produced in the second polymerisation stage is 0.1:99.9 to 20:80, that the polymer produced in the first polymerisation stage has long chain branches and that essentially no further long chain branches are formed during the second polymerisation stage.
公开/授权文献
- EP1448633B2 TWO-STEP POLYMERIZATION PROCESS 公开/授权日:2012-06-13
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