发明公开
EP1458787A1 PROCESS FOR THE PRODUCTION OF BRANCHED MELT POLYCARBONATE BY LATE ADDITION OF FRIES-INDUCING CATALYST
有权
用于生产支化熔融聚碳酸酯通过FRIES诱导催化剂后加
- 专利标题: PROCESS FOR THE PRODUCTION OF BRANCHED MELT POLYCARBONATE BY LATE ADDITION OF FRIES-INDUCING CATALYST
- 专利标题(中): 用于生产支化熔融聚碳酸酯通过FRIES诱导催化剂后加
-
申请号: EP02789615.8申请日: 2002-11-12
-
公开(公告)号: EP1458787A1公开(公告)日: 2004-09-22
- 发明人: KARLIK, Dennis , BRACK, Hans, Peter , VERHOOGT, Hendrik , LEMMON, John, Patrick , KAMPS, Jan, Henk , SEDEREL, Willem, Lodewijk , GOOSSENS, Johannes, Martinus, Dina
- 申请人: GENERAL ELECTRIC COMPANY
- 申请人地址: 1 River Road Schenectady, NY 12345 US
- 专利权人: GENERAL ELECTRIC COMPANY
- 当前专利权人: GENERAL ELECTRIC COMPANY
- 当前专利权人地址: 1 River Road Schenectady, NY 12345 US
- 代理机构: Szary, Anne C.
- 优先权: US683410 20011221
- 国际公布: WO2003057758 20030717
- 主分类号: C08G64/30
- IPC分类号: C08G64/30
摘要:
The invention relates to a method for the production of a branched polycarbonate composition, having increased melt strength, by late addition of branch-inducing catalysts to the polycarbonate oligomer in a melt polycondensation process. Surprisingly, it has been found that by adding branch-inducing catalysts, such as alkali metal compounds and/ or alkaline earth metal compounds, to the melt polycarbonate oligomer at a later stage of the melt polycondensation process, preferably after the oligomer has reached an average molecular weight of between about 3,000 and 30,000 g/mole, a unique branched polycarbonate composition is formed that has improved properties. It is believed that the addition of the branch-inducing catalysts at the later stages of the process produces a branched polycarbonate composition having longer chains between the branching points, and thus a new composition is produced. The invention also relates to various applications of the branched polycarbonate composition.
公开/授权文献
信息查询