发明公开
- 专利标题： VERFAHREN ZUR HERSTELLUNG VON BUTADIEN AUS N-BUTAN
- 专利标题（英）： Method for the production of butadiene from n-butane
- 专利标题（中）： PROCESS FOR制丁二烯由正丁烷
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申请号： EP03763815.2申请日： 2003-07-10
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公开(公告)号： EP1523462A1公开(公告)日： 2005-04-20
- 发明人: SCHINDLER, Götz-Peter , WALSDORFF, Christian , HARTH, Klaus , HIBST, Hartmut
- 申请人： BASF AKTIENGESELLSCHAFT
- 申请人地址： 67056 Ludwigshafen DE
- 专利权人： BASF AKTIENGESELLSCHAFT
- 当前专利权人： BASF AKTIENGESELLSCHAFT
- 当前专利权人地址： 67056 Ludwigshafen DE
- 代理机构： Isenbruck, Günter, Dr.
- 优先权： DE10231632 20020712
- 国际公布： WO2004007408 20040122
- 主分类号： C07C5/333
- IPC分类号： C07C5/333 ; C07C11/167
摘要：
The invention relates to a method for the production of butadiene from n-butane comprising the steps: (a) preparation of a gas feedstream containing n-butane, (b) feeding the gas feedstream containing n-butane into a first dehydrogenation zone with non-oxidative catalytic dehydrogenation of n-butane to give 1-butene, 2-butene and optionally butadiene, whereby a first gas product stream comprising n-butane, 1-butene, 2-butene, optionally butadiene and optionally by-products is obtained, (c) feeding the first gas product stream comprising n-butane, 1-butene, 2-butene, optionally butadiene and optionally by-products into a second dehydrogenation zone with oxidative dehydrogenation of 1-butene and 2- butene to give butadiene, whereby a second gas product stream is obtained comprising butadiene, n-butane, steam and optionally by-products and (d) recovery of butadiene from the second gas product stream.
公开/授权文献
- EP1523462B1 VERFAHREN ZUR HERSTELLUNG VON BUTADIEN AUS N-BUTAN 公开/授权日：2010-03-17
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