发明公开
- 专利标题: COPOLYMERES ETHYLENE/ BUTADIENE, SYSTEM CATALYTIQUE ET LES PRODUIRES ET PRODUCTION DESDITS POLYMERS
- 专利标题(英): Ethylene/butadiene copolymers, catalytic system of producing same and production of said polymers
- 专利标题(中): 乙烯/丁二烯共聚物,其制造方法催化剂和系统
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申请号: EP03776864.5申请日: 2003-10-13
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公开(公告)号: EP1554321A1公开(公告)日: 2005-07-20
- 发明人: Monteil, Vincent , SPITZ, Roger , BOISSON, Christophe
- 申请人: Société de Technologie Michelin , MICHELIN RECHERCHE ET TECHNIQUE S.A. , TOTAL PETROCHEMICALS RESEARCH FELUY
- 申请人地址: 23, rue Breschet 63000 Clermont-Ferrand FR
- 专利权人: Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.,TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人: Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.,TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人地址: 23, rue Breschet 63000 Clermont-Ferrand FR
- 代理机构: Hiebel, Robert
- 优先权: FR0212893 20021016
- 国际公布: WO2004035639 20040429
- 主分类号: C08F210/12
- IPC分类号: C08F210/12 ; C08F236/06
摘要:
The invention relates, in particular, to ethylene and butadiene copolymers and to a catalytic system which can be used for the synthesis of said copolymers. The inventive copolymers comprise a molar ratio of units derived from butatdiene which is greater than or equal to 8 %, said units comprising trans-1,2 cyclohexane chain formations, and have an average molecular mass Mn which is greater than or equal to 40 000 g/mol. According to the invention, the catalytic system consists of (i) an organometallic complex which is represented by either formula A or B , wherein: Ln represents a lanthanide and X represents a halogen. In formula A , two ligand molecules Cp1 and Cp2, which are each formed by a fluorenyl group, are linked to Ln. In formula B , a ligand molecule is linked to Ln, said molecule being formed by two fluorenyl groups Cp1 and Cp2 which are interconnected by a bridge P having formula MR2, wherein M is an element from column IVA and R is an alkyl with between 1 and 20 carbon atoms. The catalytic system also consists of (ii) a co-catalyst belonging to the group comprising a magnesium alkyl, a lithium alkyl, an aluminium alkyl, a Grignard reagent or a mixture of said components. Said catalytic system is such that the molar ratio (co-catalyst/organometallic complex) lies between 1 and 8.
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