发明公开
EP1565501A1 PROCEDE D'OBTENTION D'UN HOMOPOLYMERE DU BUTADIENE EN PRESENCE DE MONO-OLEFINE(S) A 4 ATOMES DE CARBONE
审中-公开
用于生产丁二烯HOMO聚合物中4碳原子上MONO烯烃的存在
- 专利标题： PROCEDE D'OBTENTION D'UN HOMOPOLYMERE DU BUTADIENE EN PRESENCE DE MONO-OLEFINE(S) A 4 ATOMES DE CARBONE
- 专利标题（英）： Method for obtaining a butadiene hompolymer in the presence of mono-olefin(s) with 4 carbon atoms
- 专利标题（中）： 用于生产丁二烯HOMO聚合物中4碳原子上MONO烯烃的存在
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申请号： EP03767562.6申请日： 2003-11-17
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公开(公告)号： EP1565501A1公开(公告)日： 2005-08-24
- 发明人: BARBOTIN, Fanny , RASIGADE, Jean-Philippe
- 申请人： Société de Technologie Michelin , MICHELIN RECHERCHE ET TECHNIQUE S.A.
- 申请人地址： 23 rue Breschet 63000 Clermont-Ferrand Cedex 09 FR
- 专利权人： Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.
- 当前专利权人： Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.
- 当前专利权人地址： 23 rue Breschet 63000 Clermont-Ferrand Cedex 09 FR
- 代理机构： Hiebel, Robert
- 优先权： FR0214482 20021118
- 国际公布： WO2004046213 20040603
- 主分类号： C08F36/06
- IPC分类号： C08F36/06 ; C08F136/06
摘要：
The invention concerns a method for obtaining a 1,3-butadiene homopolymer which consists in reacting a catalytic system in the presence of 1,3-butadiene and one or more mono-olefin(s) of 4 carbon atoms. The invention is characterized in that said catalytic system is based on at least: one conjugate diene monomer, one salt of one or more rare earth metals of an organic phosphoric acid, said salt being suspended in at least a saturated, inert hydrocarbon solvent of the aliphatic or alicyclic type, an alkylating agent consisting of alkylaluminium of formula AlR3 or HalR2, wherein R is an alkyl group, and a halogen donor consisting of alkylaluminium halide.
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