发明公开
- 专利标题: SYSTEME CATALYTIQUE POUR L'OBTENTION DE COPOLYMERES DIENE(S) CONJUGUE(S) / MONO-OLEFINE(S) ET CES COPOLYMERES
- 专利标题(英): Catalytic system for the production of conjugated diene/mono-olefin copolymers and copolymers thereof
- 专利标题(中): 共轭二烯和催化剂体系共聚物用于生产
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申请号: EP04763491.0申请日: 2004-07-26
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公开(公告)号: EP1656400A1公开(公告)日: 2006-05-17
- 发明人: BOISSON, Christophe , MONTEIL, Vincent , SPITZ, Roger
- 申请人: Société de Technologie Michelin , MICHELIN RECHERCHE ET TECHNIQUE S.A. , TOTAL PETROCHEMICALS RESEARCH FELUY
- 申请人地址: 23, rue Breschet 63000 Clermont-Ferrand FR
- 专利权人: Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.,TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人: Société de Technologie Michelin,MICHELIN RECHERCHE ET TECHNIQUE S.A.,TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人地址: 23, rue Breschet 63000 Clermont-Ferrand FR
- 代理机构: Hiebel, Robert
- 优先权: FR0309930 20030813
- 国际公布: WO2005028526 20050331
- 主分类号: C08F210/02
- IPC分类号: C08F210/02 ; C08F4/62
摘要:
The invention relates to a catalytic system for the copolymerisation of a conjugated diene and at least one mono-olefin, a method for production of said catalytic system, a method for production of a copolymer of a conjugated diene and at least one mono-olefin, using said catalytic system and said copolymer. The catalytic system comprises (i) an organometallic complex, represented by the following generic formula (1) {[P(Cp)(F1)Ln(X)(Lx)}p, where Ln is a lanthanide atom to which is bonded a ligand molecule with cyclopentadienyl (Cp) and fluorenyl (F1) groups, bonded to each other by means of a bridge (P) of formula MR1R2, where M is an element of the IVA group and where R1 and R2, independently = an alkyl group with 1 to 20 C atoms, or cycloalkyl or phenyl groups with 6 to 20 C atoms, where X = a halogen which can be chlorine, fluorine, bromine, or iodine, where L comprises an optional complexing molecule such as an ether and, optionally a substantially less complexing molecule such as toluene, where p is a whole natural number equal to or greater than 1 and x is equal to or greater than 0 and (ii) a co-catalyst belonging to the group of alkyl magnesiums, alkyl lithiums, alkyl aluminiums, Grignard reagents and mixtures of said components.
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