A multi-layer sheet which has a follow-up layer being composed of a resin composition containing a resin having a melting point, which is the melting peak temperature measured by DSC, in the range of 50 to 130 °C as a primary component, and a releasing layer being composed of a resin composition containing a resin having a melting point of 200 °C or higher as a primary component and being laminated on the above follow-up layer, wherein when the two releasing layers of the above multi-layer sheets are closely contacted with each other under a condition of 170 °C and 3 MPa for 30 minutes, they exhibit a blocking force of 0.1 N/cm or less as measured in accordance with ASTM D1893. The multi-layer sheet is excellent in heat resistance, releasing characteristics and follow-up characteristics to an irregular surface, exhibits excellent non-staining characteristics and also can be easily disposed of after use.