- 专利标题: VERFAHREN ZUR HERSTELLUNG VON BUTADIEN
- 专利标题(英): Method for the production of butadiene
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申请号: EP04804421.8申请日: 2004-12-30
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公开(公告)号: EP1708978A1公开(公告)日: 2006-10-11
- 发明人: JOHANN, Thorsten , SCHINDLER, Götz-Peter , BRODHAGEN, Andreas , CRONE, Sven , BENFER, Regina , HILL, Thomas , DUDA, Mark
- 申请人: BASF Aktiengesellschaft
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: 67056 Ludwigshafen DE
- 代理机构: Isenbruck, Günter
- 优先权: DE10361824 20031230
- 国际公布: WO2005063658 20050714
- 主分类号: C07C5/333
- IPC分类号: C07C5/333 ; C07C11/167
摘要:
The invention relates to a method for producing butadiene from n-butane, comprising the steps of A) providing an input gas flow a containing n-butane; B) feeding said input gas flow a containing n-butane into at least one first dehydrogenation zone and dehydrogenating n-butane in a non-oxidative catalytic manner, whereby a product gas flow b containing n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary components, and optional steam is obtained; C) feeding the product gas flow b resulting from the non-oxidative catalytic dehydrogenation process and an oxygen-containing gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene, whereby a product gas flow c containing n-butane, 2-butene, butadiene, hydrogen, low-boiling secondary components, and steam is obtained, said second product gas flow c having a higher butadiene content than product gas flow b; D) eliminating hydrogen, the low-boiling secondary components, and steam, whereby a C4 product gas flow d essentially comprising n-butane, 2-butene, and butadiene is obtained; E) separating the C4 product gas flow d into a recirculation flow e1 essentially comprising n-butane and 2-butene and a flow e2 substantially comprising butadiene by means of extractive distillation, and redirecting flow e1 into the first dehydrogenation zone.
公开/授权文献
- EP1708978B1 VERFAHREN ZUR HERSTELLUNG VON BUTADIEN 公开/授权日:2010-05-05
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