Disclosed herein is a structure of layering unit cells for a lithium polymer battery, in which electrode terminals are provided on surfaces of the respective unit cells for the lithium polymer battery, and are alternately layered, thus allowing the unit cells to be connected in series through only a layering operation without an additional connecting device. The battery system includes first and second unit cells each having a pouch and anode and cathode terminals which are connected to a surface of the pouch and are oppositely bent in upward and downward directions. In this case, the cathode terminal of the second unit cell is directly connected to the anode terminal of the first unit cell.