发明公开
EP2022772A1 Process for converting methane into liquid alkane mixtures
审中-公开
Verfahren zur Umwandlung von Methan在flüssigeAlkangemische
- 专利标题: Process for converting methane into liquid alkane mixtures
- 专利标题(中): Verfahren zur Umwandlung von Methan在flüssigeAlkangemische
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申请号: EP07253120.5申请日: 2007-08-09
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公开(公告)号: EP2022772A1公开(公告)日: 2009-02-11
- 发明人: Basset, Jean-Marie , Taoufik, Mostafa , Thivolle-Cazat, Jean , Chakka, Sudhakar
- 申请人: BP OIL INTERNATIONAL LIMITED
- 申请人地址: Chertsey Road Sunbury-on-Thames, Middlesex TW16 7BP GB
- 专利权人: BP OIL INTERNATIONAL LIMITED
- 当前专利权人: BP OIL INTERNATIONAL LIMITED
- 当前专利权人地址: Chertsey Road Sunbury-on-Thames, Middlesex TW16 7BP GB
- 代理机构: De Kezel, Eric
- 主分类号: C07C2/76
- IPC分类号: C07C2/76 ; C07C6/08 ; C07C9/00
摘要:
The present invention relates to a process for converting methane into a liquid mixture of (C 3+ ) alkanes having 3 carbon atoms and more, preferably (C 4+ ) alkanes having 4 carbon atoms and more, especially (C 5+ ) alkanes having 5 carbon atoms and more. It comprises a stage (1) comprising converting methane into acetylene, performed by submitting methane to a thermal cracking reaction, so as to form a reaction mixture (M1) comprising acetylene and hydrogen, a stage (2) comprising converting acetylene into ethane, performed by contacting the acetylene or the reaction mixture (M1) previously obtained with hydrogen in the presence of a hydrogenation catalyst (C1), so as to form a reaction mixture (M2) comprising ethane, a stage (3) comprising simultaneous ethane self- and cross-metathesis reactions performed by contacting the ethane or the reaction mixture (M2) previously obtained with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, so as to form a reaction mixture (M3) comprising methane and a mixture of the (C 3+ ), preferably the (C 4+ ), especially the (C 5+ ) alkanes, and a stage (4) comprising fractionating the reaction mixture (M3) so as to separate and to isolate said mixture in liquid form. Preferably, the methane is also separated in stage (4) and recycled into stage (1) for methane conversion into acetylene
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