发明公开
- 专利标题: AUF NACHWACHSENDEN ROHSTOFFEN BASIERENDE ACRYLSÄURE UND WASSERABSORBIERENDE POLYMERGEBILDE SOWIE VERFAHREN ZU DEREN HERSTELLUNG MITTELS DEHYDRATISIERUNG
- 专利标题(英): Acrylic acid based on renewable raw materials, water-absorbing polymer structures, and method for the production thereof by means of dehydration
- 专利标题(中): 可再生资源的丙烯酸基和吸收聚合物的结构和方法用于生产通过脱水
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申请号: EP07802811.5申请日: 2007-08-22
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公开(公告)号: EP2061742A2公开(公告)日: 2009-05-27
- 发明人: BUB, Günther , MOSLER, Jürgen , KUPPINGER, Franz-Felix , SABBAGH, Andreas , STOCHNIOL, Guido , SAUER, Jörg , WINTERBERG, Markus , KNIPPENBERG, Udo , LATOSCHINSKI, Günter , FURNO, Franck
- 申请人: Evonik Stockhausen GmbH
- 申请人地址: Bäkerpfad 25 47805 Krefeld DE
- 专利权人: Evonik Stockhausen GmbH
- 当前专利权人: Evonik Stockhausen GmbH
- 当前专利权人地址: Bäkerpfad 25 47805 Krefeld DE
- 代理机构: Lang, Arne
- 优先权: DE102006039205 20060822
- 国际公布: WO2008023040 20080228
- 主分类号: C07C45/52
- IPC分类号: C07C45/52 ; C07C51/25 ; B01J8/02 ; B01J19/00 ; C08F2/20 ; C08F20/06 ; C08F120/06 ; C08F220/06 ; C08L33/02 ; C09D133/02 ; C07C47/22 ; C07C57/04
摘要:
The invention relates to a method comprising at least the following steps: a) glycerin is dehydrated so as to obtain a dehydrated product containing acrolein; b) the dehydrated product is subjected to gas phase oxidation so as to obtain a monomer gas containing acrylic acid; c) the monomer gas is contacted with a quenching agent so as to obtain a quench phase containing acrylic acid; d) the quench phase is reprocessed so as to obtain a monomer phase containing acrylic acid. A liquid phase (a1) and a gas phase (a2) are provided during the dehydration process, a plurality of gas bubbles being produced in the liquid phase (a1). The invention further relates to a method for producing polymers by polymerizing acrylic acid, preferably for producing water-absorbing polymers, the water-absorbing polymers obtained by means of said method, a compound, a method for producing a compound, the compound obtained by means of said method, and other chemical products.
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