发明公开
EP2077983A1 PROCESS AND APPARATUS FOR ALKYLATION OF AROMATIC COMPOUND WITH ALIPHATIC MONO-OLEFIN COMPOUND OF 8 TO 18 CARBON ATOMS
有权
的方法和装置具有脂肪族MONOOLEFINVERBINDUNG具有8至18个碳原子的芳族化合物进行烷基化
- 专利标题: PROCESS AND APPARATUS FOR ALKYLATION OF AROMATIC COMPOUND WITH ALIPHATIC MONO-OLEFIN COMPOUND OF 8 TO 18 CARBON ATOMS
- 专利标题(中): 的方法和装置具有脂肪族MONOOLEFINVERBINDUNG具有8至18个碳原子的芳族化合物进行烷基化
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申请号: EP07854488.9申请日: 2007-10-29
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公开(公告)号: EP2077983A1公开(公告)日: 2009-07-15
- 发明人: RILEY, Mark G.
- 申请人: UOP LLC
- 申请人地址: 25 East Algonquin Road, P.O. Box 5017 Des Plaines, IL 60017-5017 US
- 专利权人: UOP LLC
- 当前专利权人: UOP LLC
- 当前专利权人地址: 25 East Algonquin Road, P.O. Box 5017 Des Plaines, IL 60017-5017 US
- 代理机构: Hayes, Adrian Chetwynd
- 优先权: US863441P 20061030
- 国际公布: WO2008055116 20080508
- 主分类号: C07C2/56
- IPC分类号: C07C2/56
摘要:
Continuous processes for monoalkylating aromatic compound with an aliphatic feedstock comprising aliphatic olefin of 8 to 18 carbon atoms per molecule are effected using at least 3 reaction zones (104, 106a, 106b) in series, each containing solid alkylation catalyst with effluent cooling between reaction zones (104, 106a, 106b), each of which reaction zones is supplied a portion of the fresh aliphatic feedstock, such that the Reaction Zone Delta T in each reaction zone (104, 106a, 106b) is less than 15°C. The overall aromatic compound to olefin molar ratio is less than 20:1. The alkylation product has desirable linearity and low amounts of dimers, dealkylated compounds and diaryl compounds even though a low aromatic compound to olefin molar ratio is used.
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