发明公开
EP2143704A1 An integrated process for preparing a carboxylic acid from an alkane
审中-公开
Integriertes Verfahren zur Herstellung einerCarbonsäureaus einem Alkan
- 专利标题: An integrated process for preparing a carboxylic acid from an alkane
- 专利标题(中): Integriertes Verfahren zur Herstellung einerCarbonsäureaus einem Alkan
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申请号: EP09155567.2申请日: 2009-03-19
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公开(公告)号: EP2143704A1公开(公告)日: 2010-01-13
- 发明人: Han, Scott , Ruettinger, Wolfgang , Sevon, Douglass, W.
- 申请人: Rohm and Haas Company
- 申请人地址: 100 Independence Mall West Philadelphia, PA 19106-2399 US
- 专利权人: Rohm and Haas Company
- 当前专利权人: Rohm and Haas Company
- 当前专利权人地址: 100 Independence Mall West Philadelphia, PA 19106-2399 US
- 代理机构: Kent, Venetia Katherine
- 优先权: US134458P 20080710
- 主分类号: C07C51/25
- IPC分类号: C07C51/25 ; C07C57/055 ; C07C253/26
摘要:
The present invention relates to an integrated process for producing unsaturated carboxylic acids from the corresponding C 2 -C 4 alkane. The process begins with integrated catalytic reactions comprising endothermic soft oxidant conversion (SOC) and exothermic selective hydrogen combustion (SHC) which cumulatively convert a C 2 -C 4 alkane to its corresponding C 2 -C 4 alkene in a product stream substantially free of hydrogen. Heat from the exothermic selective hydrogen combustion reaction zone is recovered and recycled back upstream to the endothermic soft oxidant conversion reaction zone. The hydrogen-free alkene products of the thermally integrated SOC/SHC reactions are then provided to a catalytic vapor phase partial oxidation process for conversion of the alkene to the corresponding unsaturated carboxylic acid or nitrile. Unreacted alkene and carbon dioxide are recovered from the oxidation product stream and recycled back to the thermally integrated soft oxidant conversion reactions.
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