发明授权
- 专利标题: METHOD FOR SPINNING AND WASHING ARAMID FIBER AND RECOVERING SULFURIC ACID
- 专利标题(中): 方法自旋和芳纶纤维洗涤回收选自硫酸
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申请号: EP08842223.3申请日: 2008-10-10
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公开(公告)号: EP2205781B1公开(公告)日: 2012-06-20
- 发明人: KALSBEEK, Esther Christina , BRUINING, Wessel Joseph
- 申请人: Teijin Aramid B.V.
- 申请人地址: Velperweg 76 6824 BM Arnhem NL
- 专利权人: Teijin Aramid B.V.
- 当前专利权人: Teijin Aramid B.V.
- 当前专利权人地址: Velperweg 76 6824 BM Arnhem NL
- 代理机构: Heimann, Anette
- 优先权: EP07020662 20071023
- 国际公布: WO2009053254 20090430
- 主分类号: D01F13/04
- IPC分类号: D01F13/04 ; D01F6/60
摘要:
The invention pertains to a method for spinning and washing aramid fiber and for recovering sulfuric acid, using a spinning unit and a sulfuric acid recovery unit, comprising the steps: a) spinning an aramid polymer from a sulfuric acid spin dope to a yarn and coagulating the yarn in a coagulation bath having an inlet for water or diluted sulfuric acid and an outlet for sulfuric acid enriched water; b) washing the yarn with water to obtain washed yarn and washing water containing 0.5-20 wt.% sulfuric acid; c) recycling the sulfuric acid enriched water and optionally the washing water to the sulfuric acid recovery unit; d) increasing the sulfuric acid content of the recycled sulfuric acid enriched water, and optionally the washing water, by evaporation to obtain 20 to 98% sulfuric acid and water; e) mixing the 20 to 98% sulfuric acid with oleum to obtain 98-105% sulfuric acid; f) recycling the 98-105% sulfuric acid to the spinning unit for use as sulfuric acid spin dope.
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