发明公开
- 专利标题: HEAT RESISTANT THERMOPLASTIC ARTICLES INCLUDING CO-STABILIZERS
- 专利标题(中): 与KO稳定剂的耐热性热塑性塑料制品
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申请号: EP09790983.2申请日: 2009-07-30
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公开(公告)号: EP2307480A1公开(公告)日: 2011-04-13
- 发明人: PALMER, Robert, J. , KOBAYASHI, Toshikazu
- 申请人: E. I. du Pont de Nemours and Company
- 申请人地址: 1007 Market Street Wilmington, DE 19898 US
- 专利权人: E. I. du Pont de Nemours and Company
- 当前专利权人: E. I. du Pont de Nemours and Company
- 当前专利权人地址: 1007 Market Street Wilmington, DE 19898 US
- 代理机构: Morf, Jan Stefan
- 优先权: US137345P 20080730
- 国际公布: WO2010014785 20100204
- 主分类号: C08G69/26
- IPC分类号: C08G69/26 ; C08G69/36 ; C08K5/053 ; C08L77/00 ; C08K5/00 ; C08K5/18 ; C08K5/06 ; C08K5/103
摘要:
Disclosed is a molded or extruded thermoplastic article including a polyamide composition including (a) a polyamide resin having a melting point and/or glass transition; (b) 0.1 to 10 weight percent of one or more polyhydric alcohols having more than two hydroxyl groups and having a number average molecular weight (M
n ) of less than 2000; (c) 0.1 to 3 weight percent of one or more co-stabilizer(s) selected from the group consisting of secondary aryl amines and hindered amine light stabilizers, and mixtures thereof; (d) 10 to 60 weight percent of one or more reinforcement agents; and (e) 0 to 50 weight percent of a polymeric toughener including a reactive functional group and/or a metal salt of a carboxylic acid; wherein 4 mm test bars prepared from said polyamide composition, exposed at a test temperature at 170 °C for a test period of 500 hours have a retention of tensile strength, on average, of at least 50 percent, as compared with that of unexposed control of identical composition and shape. Further disclosed is a molded or extruded thermoplastic article, including a thermoplastic polyamide composition, wherein 4 mm test bars of said thermoplastic polyamide composition, when exposed at 210 °C for a test period of 500 hours, have a retention of tensile strength of at least 70 percent. Disclosed is a molded or extruded thermoplastic article including a polyamide composition including (a) a polyamide resin having a melting point and/or glass transition; (b) 0.1 to
n ) of less than 2000; (c) 0.1 to 3 weight percent of one or more co-stabilizer(s) selected from the group consisting of secondary aryl amines and hindered amine light stabilizers, and mixtures thereof; (d) 10 to 60 weight percent of one or more reinforcement agents; and (e) 0 to 50 weight percent of a polymeric toughener including a reactive functional group and/or a metal salt of a carboxylic acid; wherein 4 mm test bars prepared from said polyamide composition, exposed at a test temperature at 170 °C for a test period of 500 hours have a retention of tensile strength, on average, of at least 50 percent, as compared with that of unexposed control of identical composition and shape. Further disclosed is a molded or extruded thermoplastic article, including a thermoplastic polyamide composition, wherein 4 mm test bars of said thermoplastic polyamide composition, when exposed at 210 °C for a test period of 500 hours, have a retention of tensile strength of at least 70 percent. Disclosed is a molded or extruded thermoplastic article including a polyamide composition including (a) a polyamide resin having a melting point and/or glass transition; (b) 0.1 to
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