发明公开
- 专利标题: A CONTINUOUS PROCESS FOR THE PRODUCTION OF A SUPERABSORBENT POLYMER
- 专利标题(中): 连续法生产高吸水性聚合物
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申请号: EP09818792.5申请日: 2009-10-01
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公开(公告)号: EP2341950A1公开(公告)日: 2011-07-13
- 发明人: FRICKER, Daniel , GARTNER, Herbert, Alfons , HAGER, Marc , HARREN, Jörg , KOHLER, Hans-Peter , PLÖCHINGER, Harald
- 申请人: Evonik Stockhausen GmbH
- 申请人地址: Bäkerpfad 25 47805 Krefeld DE
- 专利权人: Evonik Stockhausen GmbH
- 当前专利权人: Evonik Stockhausen GmbH
- 当前专利权人地址: Bäkerpfad 25 47805 Krefeld DE
- 代理机构: Polypatent
- 优先权: EP08017544 20081007
- 国际公布: WO2010040466 20100415
- 主分类号: A61L15/60
- IPC分类号: A61L15/60 ; C08F2/10 ; C08F20/06 ; C08J11/00
摘要:
The present invention relates to a continuous process for the production of a superabsorbent polymer comprising: (a) providing an acidic liquid aqueous monomer mixture containing dissolved oxygen, whereby the monomers are selected to provide after polymerization a superabsorbent polymer, (b) continuously feeding said aqueous monomer mixture to a reactor, (c) introducing a source of carbonate or hydrogen carbonate into said aqueous monomer mixture prior to entry into the reactor thereby forming a gas phase comprising carbon dioxide and at least a part of said dissolved oxygen, said gas phase being dispersed in the liquid phase, (d) subjecting the gas/liquid mixture to at least partial phase separation immediately prior to or after entry into the reactor and at least partially removing the separated gaseous phase, (e) subjecting the liquid phase in the reactor to free-radical polymerization to obtain the superabsorbent polymer, and (f) continuously removing the superabsorbent polymer from the reactor.
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