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EP2351725A1 A METHOD FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND 有权
Verfahren zur Herstellung von Ethylenglycol aus einer Polyhydroxidverbindung

A METHOD FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND
摘要:
A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stirring. The catalyst includes one or more first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture, and/or alloy thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof.The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300°C for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
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