发明公开
EP2351725A1 A METHOD FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND
有权
Verfahren zur Herstellung von Ethylenglycol aus einer Polyhydroxidverbindung
- 专利标题: A METHOD FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND
- 专利标题(中): Verfahren zur Herstellung von Ethylenglycol aus einer Polyhydroxidverbindung
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申请号: EP09828605.7申请日: 2009-11-05
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公开(公告)号: EP2351725A1公开(公告)日: 2011-08-03
- 发明人: ZHANG, Tao , ZHENG, Mingyuan , WANG, Aiqin , JI, Na , PANG, Jifeng , TAI, Zhijun , ZHOU, Likun , CHEN, Jingguang , WANG, Xiaodong
- 申请人: Dalian Institute Of Chemical Physics, Chinese Academy of Sciences
- 申请人地址: No.457 Zhongshan Road Dalian Liaoning 116023 CN
- 专利权人: Dalian Institute Of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人: Dalian Institute Of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人地址: No.457 Zhongshan Road Dalian Liaoning 116023 CN
- 代理机构: Stuart, Ian Alexander
- 优先权: CN200810229065 20081126
- 国际公布: WO2010060345 20100603
- 主分类号: C07C29/00
- IPC分类号: C07C29/00 ; C07C31/20
摘要:
A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stirring. The catalyst includes one or more first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture, and/or alloy thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof.The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300°C for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
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