The present invention proposes a posture-adjustable solar-collecting window blind, which can adjust the position of solar cells to better collect solar energy. In the window blind, a solar detector and an ampere meter are used to detect the relationship between the incident angle of sunlight and an optimal arrangement of the solar detector. The relationship can be further used to adjust the positions of the plurality of solar cells. Furthermore, the window blind comprises a light sensor to detect the light intensity of a target area, which can be complementarily used to adjust the position of the plurality of solar cells.