发明公开
- 专利标题: VERFAHREN ZUR OBERFLÄCHEN-DEKONTAMINATION
- 专利标题(英): Method for decontaminating surfaces
- 专利标题(中): 方法表面消毒
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申请号: EP10795259.0申请日: 2010-12-01
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公开(公告)号: EP2417606A1公开(公告)日: 2012-02-15
- 发明人: GASSEN, Rainer , ZEILER, Bertram
- 申请人: Areva NP GmbH
- 申请人地址: Paul-Gossen-Strasse 100 91052 Erlangen DE
- 专利权人: Areva NP GmbH
- 当前专利权人: Areva NP GmbH
- 当前专利权人地址: Paul-Gossen-Strasse 100 91052 Erlangen DE
- 代理机构: Mörtel & Höfner
- 优先权: DE102009047524 20091204
- 国际公布: WO2011067271 20110609
- 主分类号: G21F9/00
- IPC分类号: G21F9/00 ; G21F9/12 ; G21F9/28 ; G21F9/30 ; C22B60/02
摘要:
The invention relates to a method for chemically decontaminating the surface of a metal component of the primary circuit of a pressurized-water reactor, said surface comprising an oxide layer. The method is divided into two process stages and is further implemented as follows: - in the first process stage, at least one treatment cycle is performed, comprising an oxidation step, a reduction step, and a subsequent first decontamination step, wherein the component is treated in the oxidation step with an aqueous solution comprising an oxidizing agent, which converts trivalent chrome present in the oxide layer into hexavalent chrome; the component is treated in the reduction step with an aqueous solution comprising a reducing agent for reducing excess oxidation agent from the oxidation step; the component is treated in the first decontamination step with an aqueous solution comprising exclusively or predominantly at least one decontamination acid that forms no antisoluble deposits with metal ions present in the solution, in particular bivalent metal ions; and the solution is fed through an ion exchanger for removing metal ions present in the solution, which metal ions originate from the oxide layer and/or the base metal of the component, - in the second process stage, at least one treatment cycle is performed, comprising a second decontamination step, wherein the component is treated with an aqueous solution comprising exclusively or predominantly oxalic acid as a decontamination acid.
公开/授权文献
- EP2417606B1 VERFAHREN ZUR OBERFLÄCHEN-DEKONTAMINATION 公开/授权日:2013-02-20
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