发明公开
- 专利标题： PROCEDE DE PREPARATION DE SOLIDES FONCTIONNALISES HYBRIDES A MATRICE ORGANIQUE-INORGANIQUE PORTANT UN CYCLE TRIAZOLE
- 专利标题（英）： Method for preparing organic/inorganic hybrid functionalized solids having a triazole ring
- 专利标题（中）： 用于生产有机/无机杂化功能化的固含量，三唑
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申请号： EP10781927.8申请日： 2010-10-06
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公开(公告)号： EP2491046A1公开(公告)日： 2012-08-29
- 发明人: SAVONNET, Marie , FARRUSSENG, David , PINEL, Catherine , BAZER-BACHI, Delphine , BATS, Nicolas , LECOCQ, Vincent
- 申请人： IFP Energies nouvelles , CNRS , Universite Claude Bernard Lyon 1
- 申请人地址： 1 & 4, avenue de Bois-Préau 92852 Rueil-Malmaison Cedex FR
- 专利权人： IFP Energies nouvelles,CNRS,Universite Claude Bernard Lyon 1
- 当前专利权人： IFP Energies nouvelles,CNRS,Universite Claude Bernard Lyon 1
- 当前专利权人地址： 1 & 4, avenue de Bois-Préau 92852 Rueil-Malmaison Cedex FR
- 优先权： FR0905107 20091023
- 国际公布： WO2011048281 20110428
- 主分类号： C07F3/00
- IPC分类号： C07F3/00 ; C07F5/00 ; C07F5/06 ; C07F19/00
摘要：
The invention relates to a method for preparing, from a hybrid solid having an organic/inorganic matrix, MOF-HH
2 , a hybrid crystallized functionalized solid having an organic/inorganic matrix and at least one reactive group containing a triazole ring, said method including: i) introducing, into a polar solvent S1, said hybrid crystallized solid IvIOF-NH
2 , at least one organic compound Q containing an azide N
3 function and at least one intermediate reactant R containing a nitrite NO
2 function; ii) reacting said reaction mixture; iii) introducing, into the reaction medium, at least one reactant A having an alkyne function or an activated cyanide function, at least one Cu catalyst C and at least one polar solvent S2; iv) reacting said reaction mixture; v) filtration and then washing; and vi) drying said hybrid crystallized functionalized solid.
2 , a hybrid crystallized functionalized solid having an organic/inorganic matrix and at least one reactive group containing a triazole ring, said method including: i) introducing, into a polar solvent S1, said hybrid crystallized solid IvIOF-NH
2 , at least one organic compound Q containing an azide N
3 function and at least one intermediate reactant R containing a nitrite NO
2 function; ii) reacting said reaction mixture; iii) introducing, into the reaction medium, at least one reactant A having an alkyne function or an activated cyanide function, at least one Cu catalyst C and at least one polar solvent S2; iv) reacting said reaction mixture; v) filtration and then washing; and vi) drying said hybrid crystallized functionalized solid.
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