发明公开
- 专利标题: CARBOPHOSHATES AND RELATED COMPOUNDS
- 专利标题(中): 卡博磷酸盐和相关链接
-
申请号: EP11707271.0申请日: 2011-02-22
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公开(公告)号: EP2539276A1公开(公告)日: 2013-01-02
- 发明人: CEDER, Gerbrand , CHEN, Hailong , DOE, Robert, E. , HAUTIER, Geoffroy , JAIN, Anubhar , KANG, Byoungwoo
- 申请人: Massachusetts Institute of Technology
- 申请人地址: 77 Massachusetts Avenue Cambridge, MA 02139 US
- 专利权人: Massachusetts Institute of Technology
- 当前专利权人: Massachusetts Institute of Technology
- 当前专利权人地址: 77 Massachusetts Avenue Cambridge, MA 02139 US
- 代理机构: HOFFMANN EITLE
- 优先权: US306670P 20100222
- 国际公布: WO2011103554 20110825
- 主分类号: C01B25/45
- IPC分类号: C01B25/45 ; H01M4/58
摘要:
The present invention generally relates to carbophosphates and other compounds. Such compounds may be used in batteries and other electrochemical devices, or in other applications such as those described herein. One aspect of the invention is generally directed to carbophosphate compounds, i.e., compounds containing carbonate and phosphate ions. For example, according to one set of embodiments, the compound has a formula A
x (M)(PO
4 )
a (CO
3 )
b , where M comprises one or more cations. A may include one or more alkali metals, for example, lithium and/or sodium. In some cases, x is greater than about 0.1, a is between about 0.1 and about 5.1, and b is between about 0.1 and about 5.1. In certain embodiments, the compound may have a unit cell atomic arrangement that is isostructural to to unit cells of the minerals sidorenkite, bonshtedtite, bradleyite, crawfordite, or ferrotychite. In some embodiments, the compound may have a formula A
x (M)(YO
4 )
a (XO
3 )
b , where A comprises one or more alkali metals, M comprises one or more cations, X includes B, C, and/or N, and Y includes Si, P, As, S, V, Nb, Mo, and/or W. In some cases, x is greater than about 0.1, a is between about 0.1 and about 5.1, and b is between about 0.1 and about 5.1. Other aspects of the invention are generally directed to techniques for making or using such compounds, kits involving such compounds, and the like.
x (M)(PO
4 )
a (CO
3 )
b , where M comprises one or more cations. A may include one or more alkali metals, for example, lithium and/or sodium. In some cases, x is greater than about 0.1, a is between about 0.1 and about 5.1, and b is between about 0.1 and about 5.1. In certain embodiments, the compound may have a unit cell atomic arrangement that is isostructural to to unit cells of the minerals sidorenkite, bonshtedtite, bradleyite, crawfordite, or ferrotychite. In some embodiments, the compound may have a formula A
x (M)(YO
4 )
a (XO
3 )
b , where A comprises one or more alkali metals, M comprises one or more cations, X includes B, C, and/or N, and Y includes Si, P, As, S, V, Nb, Mo, and/or W. In some cases, x is greater than about 0.1, a is between about 0.1 and about 5.1, and b is between about 0.1 and about 5.1. Other aspects of the invention are generally directed to techniques for making or using such compounds, kits involving such compounds, and the like.
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