发明公开
EP2617699A1 METHOD FOR DEHYDRATING HYDROFLUOROCARBON OR HYDROCHLOROFLUOROCARBON, AND METHOD FOR PRODUCING 1,3,3,3-TETRAFLUOROPROPANE USING SAID DEHYDRATING METHOD 有权
的脱水方法的氢氟碳化合物或HYDROCHLORFLUORKARBONAT和工艺用于生产1,3,3,3-四氟丙烷在这个过程中脱水

METHOD FOR DEHYDRATING HYDROFLUOROCARBON OR HYDROCHLOROFLUOROCARBON, AND METHOD FOR PRODUCING 1,3,3,3-TETRAFLUOROPROPANE USING SAID DEHYDRATING METHOD
摘要:
There are provided a dehydration process of a hydrofluorocarbon or hydrochlorofluorocarbon, which can be done by a simple equipment, and a continuous production process of 1,3,3,3-tetrafluoropropene using the dehydration process. The dehydration process of the hydrofluorocarbon or hydrochlorofluorocarbon includes cooling the hydrofluorocarbon or hydrochlorofluorocarbon in gaseous form containing at least water by a heat exchanger, thereby condensing and liquefying the hydrofluorocarbon or hydrochlorofluorocarbon while freezing and solidifying the water. The production method of the 1,3,3,3-tetrafluoropropene includes a first step for fluorinating 1-chloro-3,3,3-trifluoropropene with hydrogen fluoride to obtain a mixture of the 1,3,3,3-tetrafluoropropene, unreacted 1-chloro-3,3,3-trifluoropropene, hydrogen fluoride, hydrogen chloride and by-products, or dehydrofluorinating 1,1,1,3,3-pentafluoropropane to obtain a mixture of the 1,3,3,3-tetrafluoropropene, unreacted 1,1,1,3,3-pentafluoropropane and by-products, a second step for removing the acidic component, a third step for dehydrating the 1,3,3,3-tetrafluoropropene by the above dehydration process, and a fourth step for purifying the 1,3,3,3-tetrafluoropropene by distillation.
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