发明授权
- 专利标题: PROCESS FOR THE PREPARATION OF HETEROPHASIC PROPYLENE POLYMER COMPOSITIONS
- 专利标题(中): 制备亲油性丙烯聚合物组合物的方法
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申请号: EP12783590.8申请日: 2012-11-07
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公开(公告)号: EP2780380B1公开(公告)日: 2018-02-28
- 发明人: GALVAN, Monica , PANTALEONI, Roberto , FUSCO, Ofelia , GADDI, Benedetta , NEUMANN, Andreas , MAZZUCCO, Antonio , COLLINA, Gianni , CIARAFONI, Marco
- 申请人: Basell Poliolefine Italia S.r.l.
- 申请人地址: Via Soperga 14/A 20127 Milano IT
- 专利权人: Basell Poliolefine Italia S.r.l.
- 当前专利权人: Basell Poliolefine Italia S.r.l.
- 当前专利权人地址: Via Soperga 14/A 20127 Milano IT
- 代理机构: Colucci, Giuseppe
- 优先权: EP11189458 20111117; US201161561688P 20111118
- 国际公布: WO2013072225 20130523
- 主分类号: C08F10/06
- IPC分类号: C08F10/06 ; C08F4/651 ; C08F4/654 ; C08F2/00
摘要:
A process for the preparation of propylene polymer compositions comprising from 50 to 90 % by weight of a propylene (co)polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C 4 -C 10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25°C; and (ii) a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more ±-olefins CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.
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