发明公开
EP2935378A1 NOUVEAU PROCÉDÉ DE PRÉPARATION DE POLYMÈRES THERMO-ÉPAISSISSANTS ET NOUVEAUX COPOLYMÈRES EN PEIGNE
有权
新方法用于生产HITZEVERDICKENDEN聚合物和新颖的梳形聚合物
- 专利标题: NOUVEAU PROCÉDÉ DE PRÉPARATION DE POLYMÈRES THERMO-ÉPAISSISSANTS ET NOUVEAUX COPOLYMÈRES EN PEIGNE
- 专利标题(英): Novel method for preparing heat-thickening polymers and novel comb copolymers
- 专利标题(中): 新方法用于生产HITZEVERDICKENDEN聚合物和新颖的梳形聚合物
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申请号: EP13803178.6申请日: 2013-11-26
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公开(公告)号: EP2935378A1公开(公告)日: 2015-10-28
- 发明人: MALLO, Paul , BRAUN, Olivier
- 申请人: Societe D'Exploitation De Produits Pour Les Industries Chimiques Seppic
- 申请人地址: 75 Quai d'Orsay 75007 Paris FR
- 专利权人: Societe D'Exploitation De Produits Pour Les Industries Chimiques Seppic
- 当前专利权人: Societe D'Exploitation De Produits Pour Les Industries Chimiques Seppic
- 当前专利权人地址: 75 Quai d'Orsay 75007 Paris FR
- 代理机构: Conan, Philippe Claude
- 优先权: FR1262528 20121221
- 国际公布: WO2014096594 20140626
- 主分类号: C08F265/10
- IPC分类号: C08F265/10
摘要:
A method for preparing a comb copolymer, of which the backbone consists, for 0% molar: - Of 50% to 100% molar of monomeric units from 2-acrylamido-2-methyl-propanesulphonic acid, and up to 50% of optional backbone monomeric units, on which lateral poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) segments are grafted, said method comprising the following successive steps: -A step (a) of reacting a compound of formula (II): CH
2 =C(R2)-C(=O)-N(R3)(R4) (II), with a chain-limiting compound of formula (IIIa): HS-R1-NH2 (IIIa) or of formula (IIIb): HS-R1-C(=O)-OH (IIIb), in order to obtain a poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) telomer, of formula (Ia): H2N-R1-S-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Ia) or of formula (Ib): HO-C(=O)-R1-S-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Ib) formula (IIIa) or (IIIb) in which n represents a whole number greater than or equal to 2 and less than or equal to 100; -A step (c) of reacting the telomer of formula (Ia) or of formula (Ib) in tert-butanol with glycidyl methacrylate (IV) to obtain a solution of the macromonomer of formula (Va): CH2=C(R5)-C(=O)-NH-R1-Z-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Va) or of formula (Vb); CH2=C(R5)-C(=O)-O-(C=O)-R1-Z-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Vb); -A step (e) of copolymerising the macromonomer of formula (Va) or of formula (Vb) in tert-butanol with the ammonium salt of 2-acrylamido-2-methyl-propanesulphonic acid, and, if applicable, with the optional monomer or monomers in the desired molar proportions; novel comb copolymers.
2 =C(R2)-C(=O)-N(R3)(R4) (II), with a chain-limiting compound of formula (IIIa): HS-R1-NH2 (IIIa) or of formula (IIIb): HS-R1-C(=O)-OH (IIIb), in order to obtain a poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) telomer, of formula (Ia): H2N-R1-S-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Ia) or of formula (Ib): HO-C(=O)-R1-S-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Ib) formula (IIIa) or (IIIb) in which n represents a whole number greater than or equal to 2 and less than or equal to 100; -A step (c) of reacting the telomer of formula (Ia) or of formula (Ib) in tert-butanol with glycidyl methacrylate (IV) to obtain a solution of the macromonomer of formula (Va): CH2=C(R5)-C(=O)-NH-R1-Z-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Va) or of formula (Vb); CH2=C(R5)-C(=O)-O-(C=O)-R1-Z-{CH2-C(R2)[C(=O)N(R3)(R4)]-}n-H (Vb); -A step (e) of copolymerising the macromonomer of formula (Va) or of formula (Vb) in tert-butanol with the ammonium salt of 2-acrylamido-2-methyl-propanesulphonic acid, and, if applicable, with the optional monomer or monomers in the desired molar proportions; novel comb copolymers.
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