发明授权
EP2955187B1 SOLID POLYALUMINOXANE COMPOSITION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFIN POLYMER
有权
固体聚铝氧烷组合物,用于烯烃聚合的催化剂和用于制备烯烃聚合物的方法
- 专利标题: SOLID POLYALUMINOXANE COMPOSITION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFIN POLYMER
- 专利标题(中): 固体聚铝氧烷组合物,用于烯烃聚合的催化剂和用于制备烯烃聚合物的方法
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申请号: EP14748938.9申请日: 2014-02-07
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公开(公告)号: EP2955187B1公开(公告)日: 2018-01-31
- 发明人: TSURUGI, Kou , HANADA, Siori , SHIBAHARA, Atsushi , KAWAMURA, Kazumori , NISHINO, Fumiaki , HARADA, Yasuyuki , YAMADA, Wataru , MATSUMOTO, Akiko , HARA, Isao , NAKAMURA, Tatsuya , MUROTO, Toshihiro
- 申请人: Mitsui Chemicals, Inc.
- 申请人地址: 5-2, Higashi-Shimbashi 1-chome Minato-ku Tokyo 105-7117 JP
- 专利权人: Mitsui Chemicals, Inc.
- 当前专利权人: Mitsui Chemicals, Inc.
- 当前专利权人地址: 5-2, Higashi-Shimbashi 1-chome Minato-ku Tokyo 105-7117 JP
- 代理机构: J A Kemp
- 优先权: JP2013023266 20130208; JP2013212878 20131010
- 国际公布: WO2014123212 20140814
- 主分类号: C08F4/6592
- IPC分类号: C08F4/6592 ; C08F210/16 ; C07F5/06 ; C08G79/10
摘要:
An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).
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