发明公开
EP3106223A1 METHOD FOR PRODUCING CORE-SHELL CATALYST PARTICLES
审中-公开
VERFAHREN ZUR HERSTELLUNG VON KERN-SCHALE-KATALYSATORPARTIKELN
- 专利标题: METHOD FOR PRODUCING CORE-SHELL CATALYST PARTICLES
- 专利标题(中): VERFAHREN ZUR HERSTELLUNG VON KERN-SCHALE-KATALYSATORPARTIKELN
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申请号: EP14882348.7申请日: 2014-12-22
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公开(公告)号: EP3106223A1公开(公告)日: 2016-12-21
- 发明人: KANEKO, Keiichi , KIMURA, Hiroko , ADACHI, Makoto
- 申请人: TOYOTA JIDOSHA KABUSHIKI KAISHA
- 申请人地址: 1, Toyota-cho Toyota-shi, Aichi-ken 471-8571 JP
- 专利权人: TOYOTA JIDOSHA KABUSHIKI KAISHA
- 当前专利权人: TOYOTA JIDOSHA KABUSHIKI KAISHA
- 当前专利权人地址: 1, Toyota-cho Toyota-shi, Aichi-ken 471-8571 JP
- 代理机构: TBK
- 优先权: JP2014026748 20140214
- 国际公布: WO2015122104 20150820
- 主分类号: B01J37/34
- IPC分类号: B01J37/34 ; B01J23/44 ; B01J35/08 ; C23C18/42 ; C25D7/00 ; H01M4/86 ; H01M4/88 ; H01M4/92
摘要:
The present invention is to provide a method for producing core-shell catalyst particles with high catalytic activity per unit mass of platinum. Disclosed is a method for producing core-shell catalyst particles including a core containing palladium and a shell containing platinum and covering the shell, wherein the method includes: a step of depositing copper on the surface of the palladium-containing particles by applying a potential that is nobler than the oxidation-reduction potential of copper to the palladium-containing particles in a copper ion-containing electrolyte, and a step of forming the shell by, after the copper deposition step and inside the reaction system kept at -3°C or more and 10°C or less, substituting the copper deposited on the surface of the palladium-containing particles with platinum by bringing the copper into contact with a platinum ion-containing solution in which platinum ions and a reaction inhibitor that inhibits a substitution reaction between the copper and the platinum, are contained.
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