发明公开
- 专利标题: CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
- 专利标题(中): 将固体生物质转化为液态烃材料
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申请号: EP15732258.7申请日: 2015-06-29
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公开(公告)号: EP3164471A1公开(公告)日: 2017-05-10
- 发明人: URADE, Vikrant Nanasaheb , CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan , GOPAL, Srikant , PANCHAGNULA, Madhusudhan Rao , DEL PAGGIO, Alan Anthony
- 申请人: Shell Internationale Research Maatschappij B.V.
- 申请人地址: Carel van Bylandtlaan 30 2596 HR Den Haag NL
- 专利权人: Shell Internationale Research Maatschappij B.V.
- 当前专利权人: Shell Internationale Research Maatschappij B.V.
- 当前专利权人地址: Carel van Bylandtlaan 30 2596 HR Den Haag NL
- 代理机构: Matthezing, Robert Maarten
- 优先权: IN3235CH2014 20140701
- 国际公布: WO2016001163 20160107
- 主分类号: C10K1/00
- IPC分类号: C10K1/00 ; C10K3/04 ; C10G1/06 ; C10G1/08 ; C10G1/10 ; C10G3/00
摘要:
The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolys is reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the active metals are present in a partially sulfided form to the extent that the first hydropyrolysis catalyst composition contains sulfur in an amount of from 10 to 90% of a full stoichiometric amount; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor 25 vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1 - C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 – C3 gases.
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