发明公开
EP3237096A1 REMOVAL OF HYDROGEN SULFIDE AND SULFUR RECOVERY FROM A GAS STREAM BY CATALYTIC DIRECT OXIDATION AND CLAUS REACTION
审中-公开
催化直接氧化法和反应法去除气体硫中的硫化氢和硫回收
- 专利标题: REMOVAL OF HYDROGEN SULFIDE AND SULFUR RECOVERY FROM A GAS STREAM BY CATALYTIC DIRECT OXIDATION AND CLAUS REACTION
- 专利标题(中): 催化直接氧化法和反应法去除气体硫中的硫化氢和硫回收
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申请号: EP15817379.9申请日: 2015-12-23
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公开(公告)号: EP3237096A1公开(公告)日: 2017-11-01
- 发明人: HEISEL, Michael , MARES, Benoit
- 申请人: Prosernat
- 申请人地址: Tour Franklin 100/101 Terrasse Boieldieu 92800 Puteaux FR
- 专利权人: Prosernat
- 当前专利权人: Prosernat
- 当前专利权人地址: Tour Franklin 100/101 Terrasse Boieldieu 92800 Puteaux FR
- 代理机构: Cabinet Plasseraud
- 优先权: EP14307188 20141224; US201414582613 20141224
- 国际公布: WO2016102652 20160630
- 主分类号: B01D53/52
- IPC分类号: B01D53/52 ; B01D53/86 ; B01D53/90 ; C01B17/04 ; C10L3/10
摘要:
The present invention is directed to a process for the removal of hydrogen sulfide and sulfur recovery from a H2S-containing gas stream by catalytic direct oxidation and Claus reaction through two or more serially connected catalytic reactors, wherein a specific control of the oxygen supplement is operated. The control and improvement of the process is obtained by complementing, in each major step of the process, the H2S-containing gas stream by a suitable flow of oxygen, namely before the H2S-containing gas stream enters the Claus furnace, in the first reactor of the process and in the last reactor of the process. Especially in application in a SubDewPoint sulfur recovery process the H2S/SO2 ratio is kept constant also during switch-over of the reactors R1 and R by adding the last auxiliary oxygen containing gas directly upstream the last reactor R so that the H2S/SO2 ratio can follow the signal of the ADA within a few seconds.
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