发明公开
- 专利标题： N-SUBSTITUTED ACYCLIC ETHYLENE DIAMINES
- 专利标题（中）： N-取代的无环乙烯二胺
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申请号： EP16001896.6申请日： 2016-08-30
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公开(公告)号： EP3290401A1公开(公告)日： 2018-03-07
- 发明人: Pelckmans, Michiel Jules Y , VAN Waes, Frederik , Sels, Bert Frans , Moonen, Kristof
- 申请人： Taminco bvba
- 申请人地址： Pantserschipstraat 207 9000 Gent BE
- 专利权人： Taminco bvba
- 当前专利权人： Taminco bvba
- 当前专利权人地址： Pantserschipstraat 207 9000 Gent BE
- 代理机构： Ricker, Mathias
- 主分类号： C07C209/26
- IPC分类号： C07C209/26 ; C07C211/10
摘要：
Two alternative methods for producing at least one N-substituted acyclic ethylene diamine are provided:
Method A according to the invention comprises:
- reacting at least one reducing sugar, hydrogen and at least one primary amine NH 2 R or at least one secondary amine NHR'R" or a mixture of at least one primary amine NH 2 R and at least one secondary amine NHR'R"
- in the presence of a supported hydrogenation catalyst
- at a reaction temperature of 50°C to 200 °C, and
- at a reaction pressure being superatmospheric pressure, and wherein
- the molar ratio of the at least one primary amine and/or secondary amine : reducing sugar is at least 4:1.
Method B according to the invention comprises the steps:
1. reacting at least one reducing sugar and at least one primary amine NH 2 R or at least one secondary amine NH 2 R'R" or a mixture of at least one primary amine NH 2 R and at least one secondary amine NHR'R" in a first step, and
2. reacting the reaction mixture obtained in step 1) with hydrogen in the presence of a supported hydrogenation catalyst in a second step.
Method A according to the invention comprises:
- reacting at least one reducing sugar, hydrogen and at least one primary amine NH 2 R or at least one secondary amine NHR'R" or a mixture of at least one primary amine NH 2 R and at least one secondary amine NHR'R"
- in the presence of a supported hydrogenation catalyst
- at a reaction temperature of 50°C to 200 °C, and
- at a reaction pressure being superatmospheric pressure, and wherein
- the molar ratio of the at least one primary amine and/or secondary amine : reducing sugar is at least 4:1.
Method B according to the invention comprises the steps:
1. reacting at least one reducing sugar and at least one primary amine NH 2 R or at least one secondary amine NH 2 R'R" or a mixture of at least one primary amine NH 2 R and at least one secondary amine NHR'R" in a first step, and
2. reacting the reaction mixture obtained in step 1) with hydrogen in the presence of a supported hydrogenation catalyst in a second step.
公开/授权文献
- EP3290401B1 N-SUBSTITUTED ACYCLIC ETHYLENE DIAMINES 公开/授权日：2020-09-23
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