发明公开
EP3307806A1 METHOD FOR POLY(PHENYLENE ETHER) MANUFACTURE AND ASSOCIATED POLY(PHENYLENE ETHER)
审中-公开
聚(苯醚)制造方法及相关聚(苯醚)
- 专利标题: METHOD FOR POLY(PHENYLENE ETHER) MANUFACTURE AND ASSOCIATED POLY(PHENYLENE ETHER)
- 专利标题(中): 聚(苯醚)制造方法及相关聚(苯醚)
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申请号: EP16731436.8申请日: 2016-06-07
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公开(公告)号: EP3307806A1公开(公告)日: 2018-04-18
- 发明人: GHANTA, Madhav
- 申请人: SABIC Global Technologies B.V.
- 申请人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 专利权人: SABIC Global Technologies B.V.
- 当前专利权人: SABIC Global Technologies B.V.
- 当前专利权人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 代理机构: Lang, Johannes
- 优先权: US201562172868P 20150609
- 国际公布: WO2016200791 20161215
- 主分类号: C08G65/44
- IPC分类号: C08G65/44
摘要:
A method of making a poly(phenylene ether) comprises: in an exotherm period, continuous addition of oxygen and a monohydric phenol to a non-polar solvent and a polymerization catalyst comprising a metal salt, an amine, and a quaternary ammonium salt in a vessel, to form a polymerization mixture, wherein the oxygen and monohydric phenol are added in a mole ratio of 0.5:1 to 1.2:1; and cessation of the continuous addition of the monohydric phenol; and in a build period, continuation of oxygen addition until there is no further increase in viscosity of the polymerization mixture. A poly(phenylene ether) having an intrinsic viscosity of 0.5 to 2.0 deciliters per gram, measured in chloroform using an Ubbelohde capillary glass viscometer at 25° C., a polydispersity of 1 to 10, and a unimodal molecular weight distribution, is made by the method.
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