- 专利标题: SEMI-AROMATIC COPOLYAMIDE RESIN AND POLYAMIDE MOLDING COMPOSITION CONSISTING OF SEMI-AROMATIC COPOLYAMIDE RESIN
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申请号: EP17809167.4申请日: 2017-03-29
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公开(公告)号: EP3339351A1公开(公告)日: 2018-06-27
- 发明人: ZHANG, Chuanhui , CAO, Min , JIANG, Sujun , SHI, Zhenguo , SUN, Xueke , FAN, Liming , CHEN, Mingqin , HUANG, Mujun , HUANG, Xianbo
- 申请人: Kingfa Sci. & Tech. Co., Ltd. , Zuhai Vanteque Specialty Engineering Plastics Co., Ltd. , Shanghai Kingfa Sci.&Tech.Dvpt.Co., Ltd.
- 申请人地址: No.33 Kefeng Road Science City Guangzhou Hi-tech Industrial Development Zone Guangzhou, Guangdong 510663 CN
- 专利权人: Kingfa Sci. & Tech. Co., Ltd.,Zuhai Vanteque Specialty Engineering Plastics Co., Ltd.,Shanghai Kingfa Sci.&Tech.Dvpt.Co., Ltd.
- 当前专利权人: Kingfa Sci. & Tech. Co., Ltd.,Zuhai Vanteque Specialty Engineering Plastics Co., Ltd.,Shanghai Kingfa Sci.&Tech.Dvpt.Co., Ltd.
- 当前专利权人地址: No.33 Kefeng Road Science City Guangzhou Hi-tech Industrial Development Zone Guangzhou, Guangdong 510663 CN
- 代理机构: Haseltine Lake LLP
- 优先权: PCT/CN2016/827155 20160914
- 国际公布: WO2018049807 20180322
- 主分类号: C08G69/14
- IPC分类号: C08G69/14 ; C08G69/16 ; C08G69/36 ; C08L77/02 ; C08L77/00 ; C08L23/20 ; C08K7/14 ; C08K3/34 ; C08K5/5313
摘要:
The present invention discloses a semiaromatic copolyamide resin and a polyamide molding composition consisting of the same, consisting of following repeat units:
(A) 26 to 80 mol% of units derived from para-amino benzoic acid;
(B) 4 to 70 mol% of units derived from 11-aminoundecanoic acid or undecanolactam, and 0 to 70 mol% of units derived from other amino acids having 6 to 36 carbon atoms or units consisting of a lactam;
(C) 0 to 37 mol% of units derived from a diamine unit having 4 to 36 carbon atoms; and
(D) 0 to 37 mol% of units derived from a diacid unit having 6 to 36 carbon atoms;
wherein, (A) + (B) + (C) + (D) = 100 mol%; and molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol% simultaneously.
The semiaromatic copolyamide resin of the present invention has property advantages such as high heat resistance, improved color property, excellent flowability and low water absorption, and the polyamide molding composition consisting of the same also has obvious advantage in the properties such as heat resistance, water absorption and color.
(A) 26 to 80 mol% of units derived from para-amino benzoic acid;
(B) 4 to 70 mol% of units derived from 11-aminoundecanoic acid or undecanolactam, and 0 to 70 mol% of units derived from other amino acids having 6 to 36 carbon atoms or units consisting of a lactam;
(C) 0 to 37 mol% of units derived from a diamine unit having 4 to 36 carbon atoms; and
(D) 0 to 37 mol% of units derived from a diacid unit having 6 to 36 carbon atoms;
wherein, (A) + (B) + (C) + (D) = 100 mol%; and molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol% simultaneously.
The semiaromatic copolyamide resin of the present invention has property advantages such as high heat resistance, improved color property, excellent flowability and low water absorption, and the polyamide molding composition consisting of the same also has obvious advantage in the properties such as heat resistance, water absorption and color.
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