- 专利标题: PROCESS FOR THE PREPARATION OF MONOCHLOROACETIC ACID
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申请号: EP16779097.1申请日: 2016-10-11
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公开(公告)号: EP3362429A1公开(公告)日: 2018-08-22
- 发明人: VOS, Hendrik Jan , TOLLIN, Lars Magnus , KOOIJMAN, Cornelis
- 申请人: Akzo Nobel Chemicals International B.V.
- 申请人地址: Velperweg 76 6824 BM Arnhem NL
- 专利权人: Akzo Nobel Chemicals International B.V.
- 当前专利权人: Akzo Nobel Chemicals International B.V.
- 当前专利权人地址: Velperweg 76 6824 BM Arnhem NL
- 代理机构: Akzo Nobel Chemicals IP Group
- 优先权: EP15189637 20151013
- 国际公布: WO2017064015 20170420
- 主分类号: C07C51/363
- IPC分类号: C07C51/363 ; C07C51/43 ; C07C51/44
摘要:
The present invention pertains to a process for the chlorination of acetic acid to form monochloroacetic acid comprising the following steps a. reacting acetic acid with chlorine using acetic anhydride and/or acetyl chloride as catalyst to form a liquid phase, and a gaseous phase, - the liquid phase comprising at least monochloroacetic acid, acid chlorides, acid anhydrides and optionally un reacted acetic acid, and - the gaseous phase comprising HCI, acetic acid, monochloroacetic acid and acid chlorides, b. stripping said liquid phase at a temperature of between 120 and 180°C and a pressure between 1 and 7 bara with gaseous HCI to form a gaseous HCI stream comprising acetic acid, acid chlorides and optionally acid anhydrides and monochloroacetic acid, and a liquid stream comprising monochloroacetic acid and dichloroacetic acid; c. cooling the gaseous HCI stream comprising acetic acid, acid chlorides, acid anhydrides and optionally monochloroacetic acid to a temperature of between 10 and 60°C (preferably around 35°C), and d. feeding the cooled gaseous HCI to an absorber with acetic acid as absorber, absorbing the acetic acid, acid chlorides and optionally monochloroacetic acid forming a stream comprising acetic acid and acid chlorides.
公开/授权文献
- EP3362429B1 PROCESS FOR THE PREPARATION OF MONOCHLOROACETIC ACID 公开/授权日:2022-12-07
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