- 专利标题: A CATALYST COMPOSITION AND A PROCESS FOR MAKING ULTRA HIGH MOLECULAR WEIGHT POLY (ALPHA-OLEFIN) DRAG REDUCING AGENTS
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申请号: EP16805241.3申请日: 2016-11-14
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公开(公告)号: EP3377541A1公开(公告)日: 2018-09-26
- 发明人: ATIQULLAH, Muhammad , AL-SARKHI, Abdelsalam , AL-THENAYAN, Faisal Mohammed , AL-MALKI, Abdullah Raddad , XU, Wei , HOSSAEN, Anwar
- 申请人: Saudi Arabian Oil Company , King Fahd University of Petroleum and Minerals
- 申请人地址: Post Office Box 5000 Dhahran 31311 SA
- 专利权人: Saudi Arabian Oil Company,King Fahd University of Petroleum and Minerals
- 当前专利权人: Saudi Arabian Oil Company,King Fahd University of Petroleum and Minerals
- 当前专利权人地址: Post Office Box 5000 Dhahran 31311 SA
- 代理机构: D Young & Co LLP
- 优先权: US201562257357P 20151119
- 国际公布: WO2017087316 20170526
- 主分类号: C08F210/14
- IPC分类号: C08F210/14 ; C08F4/642 ; C08F4/651
摘要:
A method of producing ultra high molecular weight (UHMW) C4-C30 α-olefin drag reducing agent (DRA). The method includes polymerizing in a reactor a first α-olefin monomer in the presence of catalyst and hydrocarbon solvent to produce the DRA. The catalyst consists essentially of at least one tertiary monophenyl amine having a formula R1R2N-aryl, where R1 and R2 are the same or different, and each is a hydrogen, an alkyl, or a cycloalkyl group, where at least one of R1 and R2 contain at least one carbon atom; at least one titanium halide having a formula TiXm, where m is from 2.5 to 4.0 and X is a halogen containing moiety; and at least one cocatalyst having a formula AlRnY3-n where R is a hydrocarbon radical, Y is a halogen or hydrogen, and n is 1-20. Further, the catalyst is absent of a carrier or support.
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