- 专利标题: SYSTEME CATALYTIQUE COMPRENANT UN METALLOCENE DE TERRE RARE
- 专利标题(英): EP3383530A1 - Catalytic system comprising a rare-earth metallocene
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申请号: EP16806025.9申请日: 2016-11-30
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公开(公告)号: EP3383530A1公开(公告)日: 2018-10-10
- 发明人: THUILLIEZ, Julien , BOISSON, Christophe
- 申请人: Compagnie Générale des Etablissements Michelin , Centre National de la Recherche Scientifique , CPE Lyon Formation Continue et Recherche
- 申请人地址: 12 Cours Sablon 63000 Clermont-Ferrand FR
- 专利权人: Compagnie Générale des Etablissements Michelin,Centre National de la Recherche Scientifique,CPE Lyon Formation Continue et Recherche
- 当前专利权人: Compagnie Générale des Etablissements Michelin,Centre National de la Recherche Scientifique,CPE Lyon Formation Continue et Recherche
- 当前专利权人地址: 12 Cours Sablon 63000 Clermont-Ferrand FR
- 代理机构: Gandon-Pain, Sylvie
- 优先权: FR1561629 20151201
- 国际公布: WO2017093278 20170608
- 主分类号: B01J31/22
- IPC分类号: B01J31/22 ; C08F210/02 ; C08F236/06
摘要:
The present invention relates to a catalytic system based at least on a rare-earth metallocene having, as ligand, a molecule consisting of two groups selected from the group consisting of cyclopentadienyl groups substituted at least at position 2 and 5, substituted fluorenyl groups, the unsubstituted fluorenyl group and indenyl groups substituted at least at position 2, and joined by a bridge. The catalytic system makes it possible to attain copolymers of ethylene and of 1,3-butadiene comprising cyclic units containing 6 carbon atoms, with an insertion of the butadiene monomer into the copolymer in the form of the trans-1,4 unit that represents more than 50 mol% of the vinyl (1,2), 1,4 and cyclic units.
公开/授权文献
- EP3383530B1 SYSTEME CATALYTIQUE COMPRENANT UN METALLOCENE DE TERRE RARE 公开/授权日:2020-05-13
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