- 专利标题: VERFAHREN ZUR HERSTELLUNG VON ACRYLSÄURE-POLYMEREN
- 专利标题(英): EP3411416A1 - Method for producing acrylic acid polymers
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申请号: EP17702123.5申请日: 2017-02-02
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公开(公告)号: EP3411416A1公开(公告)日: 2018-12-12
- 发明人: BARTH, Johannes , FONSECA, Gledison , FAUL, Dieter , ERNST, Martin , DETERING, Jürgen , LEIFELD, Ferdinand , TUERKOGLU, Gazi
- 申请人: BASF SE
- 申请人地址: Carl-Bosch-Strasse 38 67056 Ludwigshafen am Rhein DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: Carl-Bosch-Strasse 38 67056 Ludwigshafen am Rhein DE
- 代理机构: Schuck, Alexander
- 优先权: EP16154168 20160204
- 国际公布: WO2017134128 20170810
- 主分类号: C08F2/10
- IPC分类号: C08F2/10 ; C02F5/10 ; C08F2/38 ; C08F220/06
摘要:
The invention relates to a method for producing aqueous solutions of acrylic acid polymers by polymerizing acrylic acid in feed mode with a radical starter in the presence of hypophosphite in water as a solvent, wherein (i) water and optionally acrylic acid in acidic, non-neutralized form, optionally one or more ethylenically unsaturated comonomers, optionally aqueous hypophosphite solution, and optionally initiator are introduced, (ii) acrylic acid in acidic, non-neutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous radical starter solution, and aqueous hypophosphite solution are added, (iii) after the end of the acrylic acid feed, a base is added to the aqueous solution, wherein the comonomer content does not exceed 30 wt% with respect to the total monomer content, characterized in that the acrylic acid, the aqueous radical starter solution, and the aqueous hypophosphite solution are added in such a way that, over a time period in which at least 75% of the acrylic acid is converted, the molar ratio x of acrylic acid to phosphorus-bonded hydrogen [AA]/[P-H] has a value x that is constant to ±0.5 and that lies in the range of 0.8 to 2.
公开/授权文献
- EP3411416B1 VERFAHREN ZUR HERSTELLUNG VON ACRYLSÄURE-POLYMEREN 公开/授权日:2020-04-08
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