- 专利标题: CATALYST FOR HYDROSILYLATION REACTION, HYDROGENATION REACTION, AND HYDROSILANE REDUCTION REACTION
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申请号: EP18760250.3申请日: 2018-02-27
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公开(公告)号: EP3590596A1公开(公告)日: 2020-01-08
- 发明人: NAGASHIMA, Hideo , SANAGAWA, Atsushi , KAWABATA, Shoma , NODA, Daisuke , SAKUTA, Koji
- 申请人: Kyushu University, National University Corporation , Shin-Etsu Chemical Co., Ltd.
- 申请人地址: 744, Motooka Nishi-ku Fukuoka-shi Fukuoka 8190395 JP
- 专利权人: Kyushu University, National University Corporation,Shin-Etsu Chemical Co., Ltd.
- 当前专利权人: Kyushu University, National University Corporation,Shin-Etsu Chemical Co., Ltd.
- 当前专利权人地址: 744, Motooka Nishi-ku Fukuoka-shi Fukuoka 8190395 JP
- 代理机构: Mewburn Ellis LLP
- 优先权: JP2017036946 20170228
- 国际公布: WO2018159595 20180907
- 主分类号: B01J31/22
- IPC分类号: B01J31/22 ; C07C5/03 ; C07C9/15 ; C07C15/073 ; C07C209/50 ; C07C211/27 ; C07F7/08 ; C07F7/10 ; C08G77/08 ; C07B61/00
摘要:
Provided is a catalyst which comprises a compound represented by formula (1) and which exhibits activity for at least one type of reaction selected from among hydrosilylation reaction or hydrogenation reaction with respect to an aliphatic unsaturated bond and hydrosilane reduction reaction with respect to a carbon-oxygen unsaturated bond or a carbon-nitrogen unsaturated bond. Formula (1): M n (L m ) {M represents Fe, Co, or Ni having an oxidation number of 0, L represents an isocyanide ligand represented by formula (2), n denotes an integer of 1-8, and m denotes an integer of 2-12. Formula (2): (CN) x -R 1 (R 1 represents a mono- to trivalent-organic group having 1-30 carbon atoms, optionally being substituted by a halogen atom, and optionally having interposed therein one or more atoms selected from among O, N, S, and Si; and x denotes an integer of 1-3.)}.
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