- 专利标题: ORGANIC TELLURIUM COMPOUND, METHOD FOR PRODUCING SAME, LIVING RADICAL POLYMERIZATION INITIATOR, METHOD FOR PRODUCING VINYL POLYMER, AND VINYL POLYMER
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申请号: EP18792072.3申请日: 2018-04-23
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公开(公告)号: EP3617190A1公开(公告)日: 2020-03-04
- 发明人: YAMAGO, Shigeru , ITO, Osamu
- 申请人: Kyoto University , Otsuka Chemical Co., Ltd.
- 申请人地址: 36-1, Yoshida-honmachi Sakyo-ku Kyoto-shi, Kyoto 606-8501 JP
- 专利权人: Kyoto University,Otsuka Chemical Co., Ltd.
- 当前专利权人: Kyoto University,Otsuka Chemical Co., Ltd.
- 当前专利权人地址: 36-1, Yoshida-honmachi Sakyo-ku Kyoto-shi, Kyoto 606-8501 JP
- 代理机构: Ter Meer Steinmeister & Partner
- 优先权: JP2017089092 20170428
- 国际公布: WO2018199000 20181101
- 主分类号: C07C395/00
- IPC分类号: C07C395/00 ; C08F4/00 ; C08F20/00 ; C08F26/10
摘要:
Provided is an organic tellurium compound having a versatility that, when used as a living radical polymerization initiator, it is applicable to polymerization of a vinyl monomer in an aqueous vehicle without using any surfactant or dispersant. An organic tellurium compound represented by a general formula (1),
where in the general formula (1) R 1 and R 2 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, A represents an alkali metal atom or an alkaline earth metal atom, x = 1 when A is monovalent, x = 1/2 when A is divalent, and R 3 is represented by a general formula (2),
where in the general formula (2) R 4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R 5 and R 6 each independently represent an alkylene group having 2 to 8 carbon atoms, and a represents an integer from 0 to 10.
where in the general formula (1) R 1 and R 2 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, A represents an alkali metal atom or an alkaline earth metal atom, x = 1 when A is monovalent, x = 1/2 when A is divalent, and R 3 is represented by a general formula (2),
where in the general formula (2) R 4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R 5 and R 6 each independently represent an alkylene group having 2 to 8 carbon atoms, and a represents an integer from 0 to 10.
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