- 专利标题： METALLACYCLOALKYLENE COMPLEXES AND USE FOR ALKYNE POLYMERIZATION TO CYCLIC POLYACETYLENES
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申请号： EP19193802.6申请日： 2015-06-09
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公开(公告)号： EP3623394A1公开(公告)日： 2020-03-18
- 发明人: VEIGE, Adam Steven , SARKAR, Soumya , MCGOWAN, Kevin Patrick , KUPPUSWAMY, Subramaniam , ROLAND, Christopher D.
- 申请人： University of Florida Research Foundation, Inc.
- 申请人地址： 223 Grinter Hall Gainesville, FL 32611 US
- 专利权人： University of Florida Research Foundation, Inc.
- 当前专利权人： University of Florida Research Foundation, Inc.
- 当前专利权人地址： 223 Grinter Hall Gainesville, FL 32611 US
- 代理机构： Engelhard, Markus
- 优先权： US201414299449 20140609
- 主分类号： C08F4/69
- IPC分类号： C08F4/69 ; C08F4/78 ; C08F30/08 ; C08F38/00 ; C08F38/02 ; C08G61/08
摘要：
A poly-unsaturated cyclic polymer can be prepared by the polymerization of alkyne monomers with a catalyst that is selected from trianionic pincer ligand supported metal-alkylidyne complexes, tetraanionic pincer ligand supported metal-alkynes, or tetraanionic pincer ligand supported metallacycloalkylene complexes. The [O 2 C( t BuC=)W( η 2 -HC≡ C t Bu)] (4) provides high polymerization rates and high molecular weight cyclic polymers. The poly-unsaturated cyclic polymers can be hydrogenated to saturated cyclic polymers. A cyclic polyphenylacetylene can be converted into a cyclic polystyrene.
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