发明公开
- 专利标题: CATALYST AND METHOD FOR DIRECTLY CONVERTING SYNTHESIS GAS INTO LOW-CARBON OLEFIN
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申请号: EP19743865.8申请日: 2019-01-28
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公开(公告)号: EP3744423A1公开(公告)日: 2020-12-02
- 发明人: PAN, Xiulian , JIAO, Feng , BAO, Xinhe , LI, Na
- 申请人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 申请人地址: No.457 Zhongshan Road Dalian, Liaoning 116023 CN
- 专利权人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人地址: No.457 Zhongshan Road Dalian, Liaoning 116023 CN
- 代理机构: Proi World Intellectual Property GmbH
- 优先权: CN201810079238 20180126
- 国际公布: WO2019144950 20190801
- 主分类号: B01J23/06
- IPC分类号: B01J23/06 ; B01J23/00
摘要:
The present invention relates to direct preparation of low-carbon olefins by using synthesis gas, and in particular to a catalyst and a method for directly converting synthesis gas into low-carbon olefins. In the method, synthesis gas is used as a reaction raw material and is subjected to a conversion reaction on a fixed bed or a moving bed. The catalyst is a composite catalyst, and is formed by compounding component I and component II in a mechanical mixing manner. The active ingredient of the component I is a metal oxide, and the component II is a molecular sieve having a CHA and AEI structure or one or more of metal modified CHA and/or AEI molecular sieves. The weight ratio between the active ingredient in the component I and component II is in the range of 0.1-20. The reaction process has a very high product yield and selectivity. The sum of selectivity of propylene and butylene reaches 40-75%, the sum of selectivity of low-carbon olefins including ethylene, propylene and butylene can reach 50-90%, and at the same time the selectivity of the byproduct methane is less below 15%, and thus the reaction process has good application prospects.
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