- 专利标题: FLUORINATED ORGANIC COMPOUND PRODUCTION METHOD
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申请号: EP19777301.3申请日: 2019-03-29
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公开(公告)号: EP3778548A1公开(公告)日: 2021-02-17
- 发明人: HIGASHI, Masahiro , KISHIKAWA, Yosuke , KITAMURA, Tsugio
- 申请人: DAIKIN INDUSTRIES, LTD. , Saga University
- 申请人地址: JP Osaka 530-8323 Umeda Center Building 4-12, Nakazaki-nishi 2-chome Kita-ku Osaka-shi; JP Saga-shi, Saga 840-8502 1 Honjo-machi
- 代理机构: Hoffmann Eitle
- 优先权: JP2018067382 20180330
- 国际公布: WO2019189862 20191003
- 主分类号: C07C67/307
- IPC分类号: C07C67/307 ; C07C69/757
摘要:
An object of the present invention is to provide a method for producing a fluorinated organic compound, whereby an iodosylbenzene derivative can be easily separated and recovered.
The above object can be achieved by a method for producing a fluorinated organic compound, comprising step A of fluorinating an organic compound (1) by reaction with a fluorine source (3)
in the presence of a hypervalent iodine aromatic ring compound (2a), or
in the presence of an iodine aromatic ring compound (2b) and an oxidant (2bo);
wherein the fluorine source (3) is a fluorine source (3a) represented by formula: MF n , wherein M is H, a metal of Group 1 of the periodic table, or a metal of Group 2 of the periodic table; and n is 1 or 2; and
step B of separating the iodine aromatic ring compound from a reaction liquid after step A is started.
The above object can be achieved by a method for producing a fluorinated organic compound, comprising step A of fluorinating an organic compound (1) by reaction with a fluorine source (3)
in the presence of a hypervalent iodine aromatic ring compound (2a), or
in the presence of an iodine aromatic ring compound (2b) and an oxidant (2bo);
wherein the fluorine source (3) is a fluorine source (3a) represented by formula: MF n , wherein M is H, a metal of Group 1 of the periodic table, or a metal of Group 2 of the periodic table; and n is 1 or 2; and
step B of separating the iodine aromatic ring compound from a reaction liquid after step A is started.
公开/授权文献
- EP3778548B1 FLUORINATED ORGANIC COMPOUND PRODUCTION METHOD 公开/授权日:2023-11-29
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