- 专利标题: BONDED BODY, SEPARATION MEMBRANE MODULE EQUIPPED WITH SAME, AND METHOD FOR PRODUCING ALCOHOL
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申请号: EP19844683.3申请日: 2019-08-02
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公开(公告)号: EP3831470A1公开(公告)日: 2021-06-09
- 发明人: ONUKI, Masamichi , SAKAMOTO, Naoyuki , TSUTSUMINAI, Susumu , ENDOU, Koetsu , FUJITA, Naoko , HARA, Misa , KUJIME, Masahiro , TORATANI, Nobuo
- 申请人: Mitsubishi Chemical Corporation , Japan Technological Research Association Of Artificial Photosynthetic Chemical Process
- 申请人地址: JP Chiyoda-ku Tokyo 100-8251 1-1, Marunouchi 1-chome,; JP Tokyo 101-0032 11-9 Iwamoto-cho 2-chome Chiyoda-ku
- 代理机构: Hoffmann Eitle
- 优先权: JP2018164260 20180903
- 国际公布: WO2020027337 20200206
- 主分类号: B01D71/02
- IPC分类号: B01D71/02 ; B01D69/10 ; B01D69/12 ; C07C29/152
摘要:
The present invention addresses the problem of providing a bonded body which has a high airtightness and exhibits excellent durability under high-temperature and high-pressure conditions. This problem is solved by a bonded body in which a complex of a zeolite and an inorganic porous support, and a dense member are bonded together by an inorganic glass or an inorganic adhesive. The inorganic glass or the inorganic adhesive has a thermal expansion coefficient of 30 × 10 -7 /K to 90 × 10 -7 /K, and the inorganic glass has a softening point of 550°C or lower. The present invention also addresses the problem of providing a method of efficiently producing an alcohol by installing a separation membrane in an alcohol synthesis reactor based on a bonding method that gives good sealing performance and durability under high-temperature and high-pressure conditions and in the presence of methanol vapor. This problem can be solved by an alcohol production method of obtaining an alcohol by allowing a raw material gas, which contains at least hydrogen and carbon monoxide and/or carbon dioxide, to react in the presence of a catalyst in a reactor. In the reactor for carrying out the reaction, an alcohol-selective permeable membrane bonded with a dense member is installed, and an alcohol generated by the reaction permeates and is recovered through the selective permeable membrane.
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