- 专利标题: FURAN DIACID-BASED POLYAMIDE, PREPARATION METHOD THEREFOR, AND FURAN DIACID-BASED POLYAMIDE COMPOSITION
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申请号: EP22871867.2申请日: 2022-09-15
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公开(公告)号: EP4389799A1公开(公告)日: 2024-06-26
- 发明人: YAN, Kun , XU, Xianjun , JIANG, Sujun , CAO, Min , MAI, Jiehong , YANG, Huixin , JIANG, Zhiqiang
- 申请人: Zhuhai Vanteque Specialty Engineering Plastics Co., Ltd.
- 申请人地址: CN Zhuhai City, Guangdong 519050 Shihua 9 Road, No. 177 Jinwan District, Nanshui Town
- 专利权人: Zhuhai Vanteque Specialty Engineering Plastics Co., Ltd.
- 当前专利权人: Zhuhai Vanteque Specialty Engineering Plastics Co., Ltd.
- 当前专利权人地址: CN Zhuhai City, Guangdong 519050 Shihua 9 Road, No. 177 Jinwan District, Nanshui Town
- 代理机构: dompatent von Kreisler Selting Werner - Partnerschaft von Patent- und Rechtsanwälten mbB
- 优先权: CN 2111122743 2021.09.24
- 国际申请: CN2022118965 2022.09.15
- 国际公布: WO2023045820 2023.03.30
- 主分类号: C08G69/40
- IPC分类号: C08G69/40 ; C08L77/06 ; C08K5/5313 ; C08K5/3492 ; C08K7/14 ; C08J5/10
摘要:
The present invention discloses a furan diacid-based polyamide, which is derived from the following repeating units: (A) 2,5-furandicarboxylic acid, (B) 1,4-cyclohexanedicarboxylic acid, and (C) 1,5-pentanediamine, where based on the total molar percentage of the diacid units, (A) accounts for 10-45 mol% of the diacid units. On one hand, by selecting a bio-based 2,5-furandicarboxylic acid, the furan diacid-based polyamide of the present invention is more environmentally friendly, and has the advantages of a melting point of 291-335°C and lower water absorption (a water absorption rate than that of a polyamide with the same amido bond density) ; on the other hand, the rigidity of cyclohexane is higher than that of an aromatic ring, such that more hard carbon layers can be formed during combustion. In addition, the furan diacid-based polyamide has a relatively high amido bond density, and can generate a relatively excellent synergistic effect with a flame retardant, such that the flame retardant effect is excellent under the synergistic effect of the two.
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