- 专利标题: HIGH-TAP-DENSITY FERRIC PHOSPHATE, PREPARATION METHOD THEREFOR, AND LITHIUM IRON PHOSPHATE
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申请号: EP23895547.0申请日: 2023-08-31
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公开(公告)号: EP4450457A1公开(公告)日: 2024-10-23
- 发明人: LIU, Shiqi , GUO, Miyan , XU, Shanwan , WANG, Hui , XU, Peng , WANG, Qin
- 申请人: Hubei Hongrun New Materials Co., Ltd. , Hubei Wanrun New Energy Technology Co., Ltd.
- 申请人地址: CN Ezhou, Hubei 436070 North of Binjiang 2nd Road and East of North 4th Road Gedian Development Zone; CN Shiyan, Hubei 442500 557 Tianma Avenue Yunyang Economic Development Zone
- 代理机构: Manitz Finsterwald Patent- und Rechtsanwaltspartnerschaft mbB
- 优先权: CN202310195783 20230228
- 国际公布: WO2024178933 20240906
- 主分类号: C01B25/37
- IPC分类号: C01B25/37 ; C01B25/45 ; H01M10/0525 ; H01M4/58
摘要:
The present invention belongs to the field of ferric phosphate preparation, and provides high tap density ferric phosphate, a preparation method thereof, and lithium iron phosphate. The method includes following steps: (a) feeding a ferrous sulfate solution and a phosphate solution including hydrogen peroxide simultaneously into a first reactor for mixing and reacting to obtain nucleated ferric phosphate; wherein a molar ratio of iron element to phosphorus element in the feeding process is 1:1, and a stirring speed is 500-600r/min; (b) discharging the nucleated ferric phosphate to a second reactor for growth to obtain amorphous ferric phosphate slurry, and post-processing the amorphous ferric phosphate slurry to obtain the high tap density ferric phosphate; wherein a stirring speed is 120-150r/min. The first reactor is a small-volume reactor, and the second reactor is a large-volume reactor. The present invention solves the technical problems of high production cost of ferric phosphate, easy destruction of particle crystal structure, distortion of crystal lattice, and high impurity content, and achieves the technical effect of preparation of high tap density ferric phosphate at low production cost.
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