- 专利标题: CLEAVAGE OF EPOXIDE FUNCTIONAL GROUP OF (METH)ACRYLIC EPOXIDE
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申请号: JP14971297申请日: 1997-06-06
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公开(公告)号: JPH1067690A公开(公告)日: 1998-03-10
- 发明人: CAUBERE PAUL , FORT YVES , ORTAR AGNES
- 申请人: ATOCHEM ELF SA
- 专利权人: ATOCHEM ELF SA
- 当前专利权人: ATOCHEM ELF SA
- 优先权: FR9008607 1990-07-06
- 主分类号: B01J23/22
- IPC分类号: B01J23/22 ; B01J23/28 ; B01J23/30 ; B01J27/18 ; B01J31/24 ; C07B35/06 ; C07B41/02 ; C07B61/00 ; C07C67/29 ; C07C69/54 ; C07C233/20 ; C07C327/28 ; C07D301/12 ; C07D301/14 ; C07D303/16 ; C07D303/48 ; C07D317/24 ; C07D317/30 ; C07F7/18 ; C08F20/26 ; C08F20/28 ; C08F20/32 ; C08F30/02
摘要:
PROBLEM TO BE SOLVED: To obtain a desired cleavage reaction product corresponding to the kind of a reactive compound by a slight change in reaction conditions by reacting (meth)acrylic epoxide with the reactive compound such as boron trifluoride etherate complex. SOLUTION: (A) A compound of the formula [X is O, S, etc. ; R is H or a 1-5C alkyl; R is a 2-20C alkyl(aryl) containing an oxirane group in a chain or a chain end, glycidyl, etc.] is reacted with (B) a reactive compound selected from an inorganic strong acid (B1 ), boron trifluoride etherate complex (B2 ), an acid salt in the presence of a corresponding acid (e.g. sodium acetate in the presence of acetic acid) (B3 ), a trialkyl or a trialkoxysilane halide) (e.g. trimethylchlorosilane) (B4 ) and a ketone in the presence of a cationic resin (acetone in the presence of a sulfonated resin) (B5 ). The cleavage product the component A is useful in the field of ink, adhesive, paint, coating film, resin, etc.
公开/授权文献
- JP2777127B2 公开/授权日:1998-07-16
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