发明中，金属表面上，然后任选地洗涤和/或活化，先用含锌离子，锰离子和磷酸根离子，和漂洗和/或干燥，可选地，此后钼的酸性水溶液磷化组合物处理 ，铜，银，金，钯，锡，锑，钛，锆和铪的金属离子选自由种类和/或聚胺，聚乙烯胺，聚苯胺，聚亚胺，聚乙烯亚胺，聚噻吩组成的组中选择的离子中的至少一个 和聚酯聚合物类预轧辊的，并且还含水至少选自它们的筛的混合物和共聚物中选择的一个构件的聚合物含有后 - 对于含有非基本上是镍与漂洗组合物处理的金属表面磷化的方法 它涉及。 本发明还提供了基本上镍 - 调理剂组合物不仅会涉及含有该释放后磷化组合物。

Invention, a metal surface, and then optionally washing and / or activation, first a zinc ion, treatment with an acidic aqueous phosphating composition containing manganese ions and phosphate ions, and rinsing and / or drying, optionally, after which the molybdenum deneom, copper, silver, gold, palladium, tin, antimony, titanium, at least one of the selected metal ions from the group consisting of zirconium and hafnium ion species and / or polyamine, polyethylene amine, polyaniline, poly-imine, polyethyleneimine, poly-T polymer class of thiophene and poly pre-roll, and also at least one kind of the aqueous after-containing polymer selected from the group consisting of a mixture thereof, and copolymer is essentially a metal surface treated with a rinse composition Ni--free phosphate to process It relates to a method. The present invention also provides a substantially nickel-conditioner composition will not only relates to a phosphating composition containing the after-free.