To provide a hard-amorphous-carbon-coated piston ring having low friction and excellent wear resistance and peeling resistance to reduce the fuel consumption of automobiles, an outer peripheral surface of a steel-made piston ring base material is provided with a primary layer constituted by a CrN/Cr laminate coating or a CrN/TiN laminate coating as thick as 10-60 μm, which is obtained by alternately laminating CrN-type chromium nitride and chromium metal or TiN-type titanium nitride, an intermediate layer of chromium metal and/or titanium metal as thick as 0.05-1.0 μm, and then a hard amorphous carbon coating as thick as 0.4-20 μm.