Process for the manufacture of α-iodoperfluoroalkanes and α,ω-diiodoperfluoroalkanes
Abstract:
The invention relates to a process for the manufacture of a-iodoperfluoroalkanes and α,ω-diiodoperfluoroalkanes of general formula: (1) A(C2F4)n1, wherein: A is selected from F, CF3 and I and n is an integer equal to or higher than 1, with the proviso that, when A is F, n is an integer higher than 1 said process comprising heating a mixture [mixture (M1)] containing: —a compound selected from I2, CF3I, CF3CF2I and C2F4I2; —TFE; —and CO2 at definite temperatures and concentrations of CO2.
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