• Patent Title: Process for preparing cyclic alpha-keto alcohols from cyclic alpha-keto enols
  • Application No.: US15502816
    Application Date: 2015-07-31
  • Publication No.: US10017464B2
    Publication Date: 2018-07-10
  • Inventor: Bernd SchäferWolfgang Siegel
  • Applicant: BASF SE
  • Applicant Address: DE Ludwigshafen
  • Assignee: BASF SE
  • Current Assignee: BASF SE
  • Current Assignee Address: DE Ludwigshafen
  • Agency: Drinker Biddle & Reath LLP
  • Priority: EP14180725 20140812
  • International Application: PCT/EP2015/067674 WO 20150731
  • International Announcement: WO2016/023772 WO 20160218
  • Main IPC: C07C403/24
  • IPC: C07C403/24 C07C403/08
Process for preparing cyclic alpha-keto alcohols from cyclic alpha-keto enols
Abstract:
The invention relates to a method for preparing a cyclic α-ketoalcohol, particularly a 6-hydroxycyclohexenone from a cyclic α-ketoenol, particularly a 6-hydroxycyclohexadienone, using a reducing agent. This reducing agent is selected from hydrogen gas; a secondary alcohol, formic acid and the salts of formic acid or a mixture of at least two representatives of these compound classes. The invention further comprises the use of an α-ketoenol, in particular a 6-hydroxycyclohexadienone, as intermediate for preparing astaxanthin.
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